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Disilene cation radical

Disilene Cation Radical Tetrakis(di-tbutylmethylsilyl)disilene Cation Radical Tetrakis(pentafluorophenyl)borate 35... [Pg.27]

Scheme 6.1.3.1 Synthesis of Disilene Cation Radical Tetrakis(di-fbutylinethylsilyl)disilene Cation-Radical Tetrakisj-pentafluorophenyDborate. (TPFPB = tetrakis (pentafluorophenyl) borate). Scheme 6.1.3.1 Synthesis of Disilene Cation Radical Tetrakis(di-fbutylinethylsilyl)disilene Cation-Radical Tetrakisj-pentafluorophenyDborate. (TPFPB = tetrakis (pentafluorophenyl) borate).
After review OW, the molecular structures in the solid state of 13 acyclic di-silenes, 13 endo- and exocyclic disilenes, 4 silicon-based dienes, 6 disilenes with radical, cation, and anion center, and one disilyne have been determined by X-ray analysis. Although the structural characteristics of a number of these new disilenes are summarized in a recent review by Weidenbruch,9 the structural parameters of all new disilenes reported after review OW are listed in Tables I-IV. [Pg.100]

The tetrakis(di-tbutylmethylsilyl)disilene (4) readily undergoes chemical oxidation with Ph3C BAr4 BAr4 = TPFPB = tetrakis(pentafluorophenyl)borate yielding the cation radical of the disilene (5). [Pg.35]

Scheme 7.1.3 Redox Behavior of Disilene Generating Cation Radical and the Anion Radical. Scheme 7.1.3 Redox Behavior of Disilene Generating Cation Radical and the Anion Radical.
See other pages where Disilene cation radical is mentioned: [Pg.27]    [Pg.35]    [Pg.27]    [Pg.35]    [Pg.27]    [Pg.35]    [Pg.27]    [Pg.35]    [Pg.35]    [Pg.36]    [Pg.76]    [Pg.35]    [Pg.36]    [Pg.76]    [Pg.410]    [Pg.104]    [Pg.162]    [Pg.1]    [Pg.1017]    [Pg.1]    [Pg.337]    [Pg.83]    [Pg.205]   
See also in sourсe #XX -- [ Pg.35 , Pg.36 ]

See also in sourсe #XX -- [ Pg.35 , Pg.36 ]



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