Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Direction of curvature

Hypothetical linear macromolecule consisting of an infinitely thin chain of continuous curvature the direction of curvature at any point is random. [Pg.47]

Fans are made either with axial propellers or with a variety of radial vanes. The merits of different directions of curvature of the vanes are stated in Figure 7.24 where the effect of flow rate of pressure, power, and efficiency also are illustrated. Backward curved vanes are preferable in most respects. The kinds of controls used have a marked effect on fan performance as Figure 7.23 shows. Table 7.4 shows capacity ranges and other characteristics of various kinds of... [Pg.143]

Cassel s results indicate gaseous films, the hydrocarbons giving the same direction of curvature as above, i.e. a preponderance of the 6 correction in the van der Waals type of equation but the lower alcohols and nitromethane showed opposite curvature in the F-p2 curves, except at very high pressures this indicates strong lateral adhesion the F-A relations for the adsorbed films, deducible from his results, indicate association into double molecules even at great dilutions. Butyl and iso-amyl alcohols formed adsorbed films intermediate in properties between the lower alcohols and the hydrocarbons. No lowering of tension at all was observed with water. Cassel s results differ considerably from those of other workers since the surface tension of his supposedly clean mercury was some 25 dynes lower than the best values of several other workers, and since no adsorption of water was found, there may have been a considerable amount of contamination initially on the mercury. [Pg.132]

The plots of Figure 24-15 illustrate the kinds of departures from Beer s law that occur when the absorbing system undergoes dissociation or association. Notice that the direction of curvature is opposite at the two wavelengths. [Pg.730]

Figure 5.68 Flavin/imine mechanism of UDP galactopyranose mutase. The direction of curvature of bound FADH as shown in the X-ray crystal structure is sketched. Figure 5.68 Flavin/imine mechanism of UDP galactopyranose mutase. The direction of curvature of bound FADH as shown in the X-ray crystal structure is sketched.
Here j indexes the maxima, and Yj stands for the value of Yat maximum j. The quantities Tjn and T 22 are the second partial derivatives of Tat y along the two principal directions of curvature there. [Pg.15]

The direction of oscillation can be experimentally determined with a polarizing microscope in the conoscopic mode. Colored rings are observed. The direction of curvature points perpendicular to the x-axis of the crystal, that is, perpendicular to the direction of oscillation. [Pg.106]

Ill, The direction of curvature has been discussed in 60. It was there shown that a curve is concave or convex upwards at a point (x, y) according as dPy/dx2 > or < 0. [Pg.181]

If the thumb, first, and second fingers of the left hand are held at right angles to each other, the thumb shows the direction of curvature of a positive ion in a magnetic field. [Pg.85]

That concept was extended from a theoretical standpoint by the postulation that the presence of an absorbed interfacial film requires the existence of two interfacial tensions—one at the oil-monolayer interface and a second at the water-monolayer interface. Since the two tensions will not, except in very unusual circumstances, be equal, the interfacial layer will spontaneously curve, with the direction of curvature determined by the relative magnitudes of the two tensions. Logically, the film will curve in the direction of the higher interfacial tension so that the phase associated with that interface will become the dispersed phase in the system. Unfortunately, this seemingly useful rule also falls on the sword of too many exceptions. Although such simple views of the role of the adsorbed monolayer in determining the nature of the emulsion can be quite useful, the many exceptions make them less than satisfying from a theoretical point of view. [Pg.269]

Antitropous Ovule, in which the direction of curvature is opposite to the direction of carpel closure (Fig 8.3B, see also Endress, 1994), more or less corresponding to epitropous (sensM Agardh, 1858). [Pg.185]

Compound curve n. A surface having curvature in two principal directions. Simply curved surfaces, such as cylinders and cones, having only one direction of curvature, may be cut along an element and laid flat. Compound curves, such as spheres and hyperbolic paraboloids, carmot be laid flat without distortion no matter how... [Pg.217]

In a protein containing more than one Trp residue the Stern Volmer quenching curve often shows downward curvature (Pigure hi). This would result because the less accessible Trp residues will be quenched after the more exposed residue, and will have a lower value of k. However, the direction of curvature will depend on the relative values of and tj, especially in the case of a single chromophore when upward curvafttre is observed. This is due to the fact that at a high quencher concentration diffusion controlled kinetics are not observed, and there will be an appreciable fraction of the chromophore that is surrounded by the quencher at the instant of excitation. That molecule will be immediately quenched and F will be less than that expected for a diffusion controlled process. [Pg.65]

Figure 11 Schematic representation of the formation of mono- and double-layer assembly products as described with S-layer subunits isolated from G. stearothermophilus NRS 2004/3a. This S-layer shows oblique lattice symmetry with center-to-center spacings of the morphological units of 9.4 and 11.6 nm and a base angle of 78°. The oblique lattice symmetry allows us to unambiguously determine the orientation of the constituent monolayer sheets in double-layer self-assembly products. On the oblique monolayer sheet A the axes of the two types of small (70 and 100 nm diameter) monolayer cylinders are formed as indicated. One of the axes includes an angle of 24° to the short base vector of the oblique S-layer lattice. The second axis is perpendicular to the first. Both monolayer cylinders have an identical direction of curvature. Owing to differences in the charge distribution on both the S-layers, PCF is only bound to the inner surface of both types of monolayer cylinders. Five types of double-layer self-assembly products with back-to-back orientation of the inner surface of the constituent monolayers have been found. The superimposition of sheets A and B in the double-layer assembly products of type I is demonstrated and the angular displacement of sheet B with respect to A around point X for the assembly products of type II to V is indicated. (Modified after P. Messner, D. Pum, and U.B. Sleytr. J. Ultrastruct. Mol. Struct. Res. 97 73-88,1986. With permission.)... Figure 11 Schematic representation of the formation of mono- and double-layer assembly products as described with S-layer subunits isolated from G. stearothermophilus NRS 2004/3a. This S-layer shows oblique lattice symmetry with center-to-center spacings of the morphological units of 9.4 and 11.6 nm and a base angle of 78°. The oblique lattice symmetry allows us to unambiguously determine the orientation of the constituent monolayer sheets in double-layer self-assembly products. On the oblique monolayer sheet A the axes of the two types of small (70 and 100 nm diameter) monolayer cylinders are formed as indicated. One of the axes includes an angle of 24° to the short base vector of the oblique S-layer lattice. The second axis is perpendicular to the first. Both monolayer cylinders have an identical direction of curvature. Owing to differences in the charge distribution on both the S-layers, PCF is only bound to the inner surface of both types of monolayer cylinders. Five types of double-layer self-assembly products with back-to-back orientation of the inner surface of the constituent monolayers have been found. The superimposition of sheets A and B in the double-layer assembly products of type I is demonstrated and the angular displacement of sheet B with respect to A around point X for the assembly products of type II to V is indicated. (Modified after P. Messner, D. Pum, and U.B. Sleytr. J. Ultrastruct. Mol. Struct. Res. 97 73-88,1986. With permission.)...
In a rectangluar coordinate system aligned with the principal directions of curvature, with the coordinate axes labeled and say, the transverse deflection measured from a tangent plane at = 2 = 0 is... [Pg.156]

In general, the values of principal curvature and the principal directions of curvature indicate the most essential features of the local substrate deformation. For example,... [Pg.157]

Besides the presented dimensionless numbers and quantities, the equations of motion contain angles of inclination, the drag coefficient Cd, and the angles of incidence P and 2- The angle Pi spfits the drag force into a parallel and a perpendicular part referring to the jet axis. P2 divides the radial amount into both directions of curvature. [Pg.180]

These preliminaries posed, I say that the points a and b (fig. 34), where the partial meridian curve stops, cannot, in the complete meridian curve, be points of inflection. One sees, indeed, according to the direction of the tangent at these points, that if the meridian curve took from there a contrary direction of curvature (fig. 35), the radius of curvature, in this part of the shape, would be directed inside the liquid like the normal, and that thus the quantity would become positive. [Pg.48]

Beyond the points a and b, the meridian curve thus starts by keeping a concave curvature and the same direction of curvature is maintained obviously for the same reason, as long as the curve is moving away at the same time from the axis of revolution and the axis of symmetry. But the curve cannot indefinitely continue to move away from these two axes indeed, if such were its progress, it is clear that the curvature should decrease so as to become zero, in each of the two branches, at the point located at infinity, so that at this point the radius of curvature would have an infinite value and as it would obviously be the same with the normal, the quantity + would become zero at this limit. [Pg.48]

The reason given in 64 to establish the absence of an inversion of curvature as long as the curve moves away at the same time from the axis of revolution andthe axis of symmetry, obviously still applies at the points which we have just considered, i.e. at those where the tangents are parallel with this last axis from which it follows that the curve approaches it, preserving the same direction of curvature, as fig. 38 shows, where the curve is drawn on a greater scale than the portion included in fig. 36, and where the axis of symmetry is represented by line XX . [Pg.49]

Thus our original assumption, that of a point of inflection in the part of the curve which is moving away from the axis of symmetry and approaching the axis of revolution, inevitably leads to impossibilities, and consequently the curve keeps the same direction of curvature until it leaves these conditions. [Pg.56]


See other pages where Direction of curvature is mentioned: [Pg.150]    [Pg.360]    [Pg.473]    [Pg.138]    [Pg.341]    [Pg.162]    [Pg.274]    [Pg.324]    [Pg.283]    [Pg.300]    [Pg.89]    [Pg.185]    [Pg.121]    [Pg.35]    [Pg.452]    [Pg.1625]    [Pg.2061]    [Pg.64]    [Pg.52]    [Pg.52]    [Pg.292]   
See also in sourсe #XX -- [ Pg.181 ]




SEARCH



Curvatures

© 2024 chempedia.info