Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Dirac delta function matrices

The statistical matrix may be written in the system of functions in which the coordinate x is diagonal. In one dimension, the eigenfunction of is the Dirac delta function. The expansion of (x) in terms of it is... [Pg.422]

This is an application of Fermi s golden rule. The first term is the square of the matrix element of the perturbation, which appears in all versions of perturbation theory. In the second term 8(x) denotes the Dirac delta function. For a full treatment of this function we refer to the literature [2]. Here we note that S(x) is defined such that S(x) = 0 for x 7 0 at the origin S(x) is singular such that / ( r) dx — 1. The term 8 (Ef — Ei) ensures energy conservation since it vanishes unless... [Pg.265]

For further derivations we will need the matrix element of the Dirac delta function, 8(r, , ). Using the following representation of the delta function,... [Pg.402]

The matrix elements of the total correlation function, h, are related to all pairs of atoms. The intramolecular correlation function, to, introduced here represents the shape of the molecule. 8(r) in the diagonal element is the Dirac delta function and represents the position of an atom. The function appearing in the off-diagonal element is given by,... [Pg.595]

Here we are taking into account the symmetry of the functions using the Fourier reducing property of the Dirac delta functions and are calculating the matrix elements using zero-order perturbation theory. [Pg.129]

The transition energies are not sharp but rather have finite widths due to thermal vibrations in the solid. Thus, the wave functions and the density of states can be treated as functions of energy. The wave functions can be normalized with respect to energy and a Dirac delta function used for the density of final states to insure conservation of energy. Then Einstein s A and B coefficients can be used to relate the transition matrix elements to experimentally measurable quantities such as oscillator strengths and luminescence lifetimes. For electric dipole-dipole interaction the energy transfer rate becomes... [Pg.48]

The Dirac delta functions, S, ensure that the ends of spacers, B, have the same orientation as the consecutive A rods to which they are attached. UA and Ub are the linear transformations of Sa and (1 — 4>)Sb, Sa and Sb are the orders of A and B components, respectively, the tranformation matrix being associated with the self and cross couplings ... [Pg.105]

In Fig. 9.4 we extract, as a case study from the complete atom QSI-matrix, the relevant information for the noble gases. Here the similarities were calculated using the Dirac delta function as separation operator. From these data it is clear that the similarity indices are higher, the closer the atoms are in the periodic table (smallest AZ, Z being the atomic number). The tendency noticed by Robert and Carbd in [45] is regained in the present study at a more sophisticated level. It can hence be concluded that the QSI involving p(r) and evaluated with 5(r-r ) as separation operator Q, does not generate periodicity. [Pg.158]

Here u(t) M" is the displacement vector f(t) e R" is the forcing vector M, Ke K"""" are respectively the mass matrix and stiffness and (t) is the matrix of damping kernel functions. In general M is a positive definite symmetric matrix and K is a nonnegative definite symmetric matrix. In the special case when t) = CS(t), where 5(t) is the Dirac delta function, it reduces to the classical viscous damping case with a damping matrix C. Therefore, Eq. 1 can be viewed as the generalization of the conventional viscously damped systems. [Pg.3662]


See other pages where Dirac delta function matrices is mentioned: [Pg.43]    [Pg.95]    [Pg.192]    [Pg.166]    [Pg.115]    [Pg.333]    [Pg.348]    [Pg.437]    [Pg.576]    [Pg.338]    [Pg.297]    [Pg.487]    [Pg.166]    [Pg.440]    [Pg.692]    [Pg.280]    [Pg.141]    [Pg.372]    [Pg.261]    [Pg.3159]    [Pg.41]    [Pg.307]    [Pg.227]    [Pg.641]    [Pg.225]    [Pg.215]   
See also in sourсe #XX -- [ Pg.307 ]




SEARCH



Delta

Delta function

Dirac delta

Dirac delta function matrix elements

Dirac function

Functionality matrix

Matrices Dirac

Matrix function

© 2024 chempedia.info