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1.1- diphenyl-1-nonene

Acyl halides are intermediates of the carbonylations of alkenes and organic-halides. Decarbonylation of acyl halides as a reversible process of the carbo-nylation is possible with Pd catalyst. The decarbonylation of aliphatic acid chlorides proceeds with Pd(0) catalyst, such as Pd on carbon or PdC, at around 200 °C[109,753]. The product is a mixture of isomeric internal alkenes. For example, when decanoyl chloride is heated with PdCF at 200 C in a distillation flask, rapid evolution of CO and HCl stops after I h, during which time a mixture of nonene isomers was distilled off in a high yield. The decarbonylation of phenylpropionyl chloride (883) affords styrene (53%). In addition, l,5-diphenyl-l-penten-3-one (884) is obtained as a byproduct (10%). formed by the insertion of styrene into the acyl chloride. Formation of the latter supports the formation of acylpalladium species as an intermediate of the decarbonylation. Decarbonylation of the benzoyl chloride 885 can be carried out in good yields at 360 with Pd on carbon as a catalyst, yielding the aryl chloride 886[754]. [Pg.258]

Keto esters are obtained by the carbonylation of alkadienes via insertion of the aikene into an acylpalladium intermediate. The five-membered ring keto ester 22 is formed from l,5-hexadiene[24]. Carbonylation of 1,5-COD in alcohols affords the mono- and diesters 23 and 24[25], On the other hand, bicy-clo[3.3.1]-2-nonen-9-one (25) is formed in 40% yield in THF[26], 1,5-Diphenyl-3-oxopentane (26) and 1,5-diphenylpent-l-en-3-one (27) are obtained by the carbonylation of styrene. A cationic Pd-diphosphine complex is used as the catalyst[27]. [Pg.515]

Isopropyl alcohol Methylene diphenyl diisocy. Nonene... [Pg.221]

Diels-Alder dienes 1-Acetoxybutadiene. Butadiene. Cyclopentadiene. (rans,mins-l,4-Diacetoxybutadiene. 2,5-Di-o-anisyl-3,4-diphenylcyclopentadienone. 5,5-Dimethoxy-l, 2,3,4-tetrachlorocyclopentadienone. 2,3-Dimethylbutadiene. 6,6-Dimethylfulvene (see o-Acetoxy acrylonitrile). 2,4-Dimethyl-l,3-pentadiene (see Diethyl azodicarboxylate). 2,3-Diphenyl-butadiene. 1,3-Diphenylisobenzofurane (see Potassium I-butoxide). rrans,/nus-l,4-Diphenyl-butadiene. 1,3-Diphenylisobenzofurane. Hexachlorocyclopentadiene. Isobenzofurane. l-o-Nitrophenylbutadiene-1,3. Oxepin (see Diazabicyclo[3.4.0]nonene-S). Phenylcyclone. Piperylene. n-Pyrone (see also Methyl vinyl ketone). Tetrachlorocyclopentadienone. Tetra-chlorofurane. Tetraphenylcyclopentadienone. [Pg.657]

Wittig reactions Carbomethoxymethylenetriohenylphosphorane. Cyclopropyltriphenyl-phosphonium bromide. l,5-Diazabicyclo[4.3.0]nonene-5. Diethyl cyanomethylphosphonate. p-Diphenylphosphinobenzoic acid. Diphenylsulfonium isopropylide. Diphenyl triphenyl-phosphoranylidenemethylphosphonate. Ethyl(dimethylsulfuranylidine)acetate. Ethylene oxide. Hexamethylphosphorous triamide. Methoxymethylenetriphenylphosphorane. Meth-ylenemagnesium bromide (chloride). Simmons-Smith reagent. Sodium 2-methyl-2-butoxide. [Pg.245]


See other pages where 1.1- diphenyl-1-nonene is mentioned: [Pg.87]    [Pg.393]    [Pg.540]    [Pg.588]    [Pg.639]    [Pg.773]    [Pg.127]    [Pg.131]    [Pg.87]    [Pg.393]    [Pg.540]    [Pg.588]    [Pg.639]    [Pg.773]    [Pg.127]    [Pg.131]    [Pg.241]    [Pg.366]    [Pg.366]    [Pg.811]    [Pg.408]    [Pg.172]    [Pg.336]   


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2-Nonen

Nonenal

Nonene

Nonenes

Synthesis of 1,1-diphenyl-1-nonene

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