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Dioximes phosphine

The reduction of benzofuroxans can lead to a variety of products, depending upon the conditions. Deoxygenation to benzofurazans (40) can be effected either directly, using trialkyl phosphites, -tributyl or triphenyl - phosphine, or indirectly, via o-quinone dioximes (41), using methanol and potassium hydroxide, or hydroxyl-amine and alkali. - - The dioximes may be isolated, but... [Pg.21]

A valuable route to benzofurazans is provided by deoxygenation of the corresponding benzofuroxan. This may be accomplished either directly using trialkyl phosphites, tributyl-or triphe nyl-phosphine, or indirectly via the quinone dioxime using, for example, methanol and potassium hydroxide, hydroxylamine and alkali, sodium azide in DMSO or ethylene glycol, sodium borohydride, and occasionally thermolysis alone. More detailed discussion of these reactions is included in Section 4.22.3.2.4. [Pg.419]

Complexes with Dioximes, Schiff Bases, and Other Nitrogen Ligands Complexes with Monodentate Phosphines and Related Ligands Complexes with Bidentate Phosphine, Arsine, and Related Ligands Complexes with Sulfur Ligands Nitrosyl and Thionitrosyl Complexes VII. Technetium(IV)... [Pg.1]

Phenyl acetate p-Quinone dioxime Toluene-2,4-diamine Tributyl phosphine 1,1,3-Triethoxy-3-methoxypropane Triethylene diamine Triethylenemelamine Trimethylolpropane tris-(B-(N-aziridinyl) propionate) Tris [1-(2-methyl-aziridinyl) phosphine oxide] Zinc acetylacetonate Zirconium acetate crosslinking agent, castings PEG-4 dimethacrylate crosslinking agent, coatings PEG-4 dimethacrylate... [Pg.5038]

Poly (metal bis( 1,2-hydroxyketonates), properties, 242 Polymetalloxanes, 334-341 Poly (metal phosphinates), 249-257 Poly(nortricyclene), 48 Polypyromellitamic acids polymers with Co(II), Cr(III), Cu(H), Hg(II), Mg(II), Mn(II), Ni(ll), Fe(III),orZn(II), 286 with metal acetylacetonates, 249 Polysilazanes, 332-333 Polysiloxanes, 332-333 Poly (titanomethylsiloxanes ), 3 21 Poly(p-xylylene), 7 Pcly(p-xylylidene), 7, 9-10 Poly-[Zn (II)bis (thiopicolinamides)], thermal stability of, 211 Polymeric 1,2-dioximes,... [Pg.389]


See other pages where Dioximes phosphine is mentioned: [Pg.174]    [Pg.189]    [Pg.189]    [Pg.1075]    [Pg.131]    [Pg.3537]    [Pg.117]    [Pg.522]    [Pg.3536]    [Pg.588]    [Pg.6051]    [Pg.6055]    [Pg.158]    [Pg.249]    [Pg.375]   
See also in sourсe #XX -- [ Pg.1161 ]




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