Dinuclear compounds photochemistry

Photochemistry. Two photochemical reactions have already been mentioned in other contexts, the isomerization of tra j-[PtCla(C2H4)(isoquinoline)] and the generation of dinuclear compounds by alkene loss (L = amine) ... 

Carbene Complexes Carbonyl Complexes ofthe Transition Metals Cyanide Complexes of the Transition Metals Dinuclear Organometallic Cluster Complexes Electron Transfer in Coordination Compounds Electron Transfer Reactions Theory Electronic Structure of Organometallic Compounds Luminescence Nucleic Acid-Metal Ion Interactions Photochemistry of Transition Metal Complexes Photochemistry of Transition Metal Complexes Theory Polynuclear Organometallic Cluster Complexes. 

The photochemistry of some dinuclear Cu" and Ni" compounds has been reported to result in the formation of reduced metal species and also in... 

Reviews have appeared of the photophysics of molybdenum complexes, primary and secondary processes in organometallic chemistry, flash photolysis of Pe(CO)5 and Cr(CO)g, dinuclear manganese carbonyl compounds, the photochemistry of metal complexes isolated in low temperature matrices, cluster complexes, diene complexes, photoproduction of coordinativeiy unsaturated species containing rhodium or iridium, and redox chemiluminescence of organometallic compounds.Synthetic and metal organic photochemistry in industry has also been reviewed. 

Photolysis of Fe(CO)5 in the presence of olefins leads to formation of olefin complexes which exhibit catalytic properties. The complex [Fe(cyclooctene)2 ( 0)3] catalyzes isomerization of olefins in alkene solutions. The compound Fe(C2H4)(CO)4 which is formed in the gas phase by photolysis of Fe(CO)5 and ethylene catalyzes hydrogenation of 2114. Photochemistry of the following dinuclear complex of iridium(I) is interesting ... 

---