Diisopropyl peroxydicarbonate oxidant

I. J-Diisocyanatotoluene Diisodecyl Phtbalate Diisopropanolamine Diisopropyl Ether Diisopropyl Oxide Diisopropyl Percarbonate Diisopropyl Peroxydicarbonate Sym-Diisopropylacetone Diisopropylamine... 

The reaction of thiophene and its derivatives with diisopropyl peroxydicarbonate has been investigated (74JOC504). In the presence of CuCl2 as oxidant, 2-thienyl isopropyl carbonate is formed in 70% yield (Scheme 62). In the absence of added oxidant, loss of a hydrogen atom from the a-complex radical is less efficient. 

SAFETY PROFILE Poison by intravenous route. Moderately toxic by ingestion and intraperitoneal routes. Human teratogenic effects by ingestion developmental abnormalities of the endocrine system. Experimental teratogenic and reproductive effects. Mutation data reported. Explosive reaction with charcoal + ozone, trifluoroacetyl hypofluorite, fluorine perchlorate. Violent reaction or ignition on contact with diazonium salts, diisopropyl peroxydicarbonate, bromine pentafluoride, chlorine trifluoride. Incompatible with oxidants, BrFs, FCIO, metallic salts, calomel. When heated to decomposition it emits very toxic fumes of K20 and I . See also IODIDES. 

Peroxydicarbonates s. Diisopropyl peroxydicarbonate Peroxydisnlfate s. Persulfate Peroxymaldc acid 26,136 Peroxymercuration of ethylene derivs. 26, 637 Persolfate 26,137 Peroxytrifluoroacetic acid as reagent 26, 137, 529 —/boron fluoride, oxidations with -, review 19, 161 suppl. 26 pH s. Buffer solns. 

Peroxydicarbonate s. Diisopropyl peroxydicarbonate Peroxydisulfate s. Persulfate Peroxynialeic acid, oxidations with — 17,151... 

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