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Diisobutylaluminium alkoxide

Application Matsutake alcohol (a fragrance compound in a Japanese mushroom) is synthesized by reduction of one terminal double bond by LiAlH4—Cp2TiCl2 after protection of an allylic alcohol group as a diisobutylaluminium alkoxide ... [Pg.124]

Although these catalytic partial hydrogenations of alkynes may well be regarded as the procedure of choice for (Z)-alkenes,25 other catalytic systems have been explored. These include a sodium hydride-sodium alkoxide-nickel(n) acetate reagent,26 and a sodium borohydride-palladium chloride-polyethylene glycol system.27 Diisobutylaluminium hydride (DIBAL) has also been used for the conversion of alkynes into (Z)-alkenes.28 ( )-Alkenes are formed when the internal triple bond is reduced with sodium in liquid ammonia.29... [Pg.494]

See other pages where Diisobutylaluminium alkoxide is mentioned: [Pg.780]    [Pg.136]    [Pg.136]   
See also in sourсe #XX -- [ Pg.124 ]



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Diisobutylaluminium

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