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Matsutake alcohol

Acetoxyoctadienes 47 and 48 are suitable starting materials for the synthesis of l-octen-3-ol (Matsutake alcohol) (129), a fragment component of a Japanese mushroom. The synthesis has been accomplished by two methods. In one method, the terminal double bond of 47 was hydro-... [Pg.182]

Trade Names. Matsutake alcohol (Takasago), Morillol (BSAF). [Pg.10]

The synthesis of both enantiomers of matsutake alcohol (a mushroom flavour compound) outlined in the accompanying scheme shows how the sulfinyl group was used to introduce a methylene unit via methylation and regioselective elimination steps [427],... [Pg.183]

The preparation of alkenic alcohols based on rDA processes has found application in the synthesis of natural products. Matsutake alcohol (14a (-)-( )-l-octen-3-ol), an important flavor component of mushrooms, can be prepared in high enantiomeric purity by a method that includes rDA cleavage as a key step. Asymmetric DA addition gave enantiomerically pure adducts that were modified dia-... [Pg.554]

IR-l-0cten-3-ol (Matsutake alcohol). CgH, 0, Mr 128.21, bp. 175 °C, [alg -20.2° LDjo (rat p.o.) 340 mg/kg. A typical mushrooms aroma constituent (olfactory threshold 1 ppb ) with an earthy-fungal odor impact compound in mushroom and Camem-bert flavor (see cheese flavor), but also occurring in many essential oils and flavors, e.g., in lavender, peppermint, rosemary, and thyme oil, as well as seafood flavors. Only the (/ )-enantiomer occurring in 90-97% enantiomeric excess possesses the pure fungus odor, the (S)-compound has a more vegetable-like odor. [Pg.446]

Application Matsutake alcohol (a fragrance compound in a Japanese mushroom) is synthesized by reduction of one terminal double bond by LiAlH4—Cp2TiCl2 after protection of an allylic alcohol group as a diisobutylaluminium alkoxide ... [Pg.124]

Also the secondary telomer, the 3-acetoxy-l,7-octadiene can be a useful starting material. TTie simplest natural product prepared from this telomer is Matsutake alcohol the l-octen-3-ol, a fragrant compound of a Japanese mushroom [9] (Equation 7). [Pg.143]


See other pages where Matsutake alcohol is mentioned: [Pg.183]    [Pg.1045]    [Pg.1756]    [Pg.48]    [Pg.104]    [Pg.666]    [Pg.996]    [Pg.133]    [Pg.775]    [Pg.849]    [Pg.480]    [Pg.114]    [Pg.143]   
See also in sourсe #XX -- [ Pg.10 ]

See also in sourсe #XX -- [ Pg.10 ]

See also in sourсe #XX -- [ Pg.103 , Pg.104 ]




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Matsutake alcohol synthesis

Matsutake alcohol via retro Diels-Alder reaction

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