1,1 - Dihydroperfluorooctyl methacrylate

FDA FOMA Food and Drug Administration 1,1 -dihydroperfluorooctyl methacrylate... 

FIGURE 13.17 Molecular structures of (a) poly(tert-butyl methacrylate)-i>-poly(l,l-dihydroperfluorooctyl acrylate) (PtBMA-fc-PFOMA) and (b) poly(2-tetrahydropyranyl methacrylate)-l -poly( 1,1 -dihydroperfluorooctyl methacrylate) (PHPMA-l -PFOMA). 

Poly(lH, IH-dihydroperfluorooctyl methacrylate) carbon dioxide 2009SAN... 

Hsiao, Y.-L. Maury, E. E. DeSimone, J. M. Mawson, S. M. Johnston, K. P. Dispersion Polymerization of Methyl Methacrylate Stabilized with Poly(l, 1-dihydroperfluorooctyl acrylate) in Supercritical Carbon Dioxide. Macromolecules 1995, 28, 8159-8166. 

Hsiao Yu Ling, Maury Elise E., DeSimone Joseph M., Mawson Simon, and Johnston Keith P. Dispersion polymerization of methyl methacrylate stabilized with poly (1,1-dihydroperfluorooctyl acrylate) in supercritical carbon dioxide. Macromolecules. 28 no. 24 (1995) 8159-8166. 

Poly(l,l"dihydroperfluorooctyl acrylate) 298 18.0 Poly(propyl methacrylate) 298 16.0... 

Acrylamide (ultra pure electrophoresis grade form Polysciences, Inc.) was used without further purification. Laurylacrylate (6) (Monomer-Polymer Labs) was purified by washing with 1 M NaOH followed by vacuum distillation. The 1,1-dihydroperfluorobutyl acrylate (2) and 1,1-dihydroperfluorooctyl acrylate (3) were purchased from Monomer-Polymer Laboratories and used as received. The fluorine containing surfactants and monomers, 2-(AT-ethylperfluorooctane-sulfoamido)ethylacrylate (4) and -methacrylate (5) technical grade were donated by the 3M Company. The monomers were recrystallized from MeOH. All of the solvents and salts were of reagent grade or ACS grade quality. The AMPS monomer (sodium salt Aldrich) was used as received. 

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