Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Diffusion in a Binary Critical Mixture

At a critical mixing point for a two-component liquid composed of species a and p, the order parameter is the concentration. For an incompressible fluid. [Pg.296]

This relation does not depend on Eq. (85), although the two equations agree in this case. Equation (126) immediately yields [Pg.297]

Away from the critical point, typically D/r) 10 [A A),.o(s = 0)] D decreases and 17 increases as the critical point is approached. Thus, Dk(s) may always be neglected with respect to 17 (5) on the right-hand side of Eq. (130). In the absence of mode-mode effects, 17 (s) would be independent of k and s for small fc, s, even near a critical point. Furthermore, the actual critical anomaly of 77 is weak. Thus, we expect that the substitution 17 (j) 170(0) = 17 in Eq. [Pg.298]

Equations (136) illustrate many of the salient points of mode-mode coupling. We are considering large with kc. shows a major [Pg.299]

Of course, one must always be careful not to read too much into explanations like that just given nevertheless, we do feel that a considerable amount of truth is contained in the droplet picture. We hasten to point out that the 6 in Eq. (136a), which occurs in the usual Stokes-Einstein law with stick boundary conditions, only occur because we have used O-Z theory this has been stressed by Swinney et In addition, note that droplet diffusion is a [Pg.299]


See other pages where Diffusion in a Binary Critical Mixture is mentioned: [Pg.296]   


SEARCH



A- ] mixture

Binary mixture

Binary mixture, diffusivity

Critical binary

Critical binary mixture

Diffusion binary mixtures

Diffusion in mixtures

Mixture critical

© 2024 chempedia.info