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Diffraction sphere

Using this equation, E)wald applied it to the case of the diffraction sphere which we show in the following diagram as 2.1.10. on the next page. Study this diagram carefully. In this case, the x-ray beam enters the sphere enters from the left and encounters a lattice plane, L. It is then diffracted by the angle 20 to the point on the sphere, P, where it... [Pg.38]

FIGURE 7 The Ewald sphere for diffraction in an orthogonal lattice. A projection of two layers of the lattice is given together with the relevant Miller indices of the lattice planes in reciprocal space. The Ewald diffraction sphere intersects the lattice plane (/ill, red). The diffraction condition is shown for two sets of lattice planes representing two points in the reciprocal lattice (21—1, 301). [Pg.291]

Figure 13.1 Reciprocal space (2D) representation of the diffraction condition Ewald sphere (radius 1/2), limiting sphere (radius 2/2) and PD sphere (double line, radius d ). Left Enlargement of the intersection between PD sphere and reciprocal space point, with approximating tangent plane (dash). The arrow shows the direction of expansion of the diffraction sphere during a PD measurement. Figure 13.1 Reciprocal space (2D) representation of the diffraction condition Ewald sphere (radius 1/2), limiting sphere (radius 2/2) and PD sphere (double line, radius d ). Left Enlargement of the intersection between PD sphere and reciprocal space point, with approximating tangent plane (dash). The arrow shows the direction of expansion of the diffraction sphere during a PD measurement.
For certain orientations of the crystal relative to the direction of the incident X-rays, there will be no reciprocal lattice points lying on the surface of the diffraction sphere, and therefore no diffraction from the crystal planes. [Pg.230]

Using this equation, Ewald applied it to the case of the diffraction sphere which we show in the following diagram ... [Pg.17]

The surface mean diameter is the diameter of a sphere of the same surface area-to-volume ratio as the actual particle, which is usually not a perfect sphere. The surface mean diameter, which is sometimes referred to as the Sauter mean diameter, is the most useful particle size correlation, because hydrodynamic forces in the fluid bed act on the outside surface of the particle. The surface mean diameter is directly obtained from automated laser light diffraction devices, which are commonly used to measure particle sizes from 0.5 to 600 p.m. X-ray diffraction is commonly used to measure smaller particles (see Size TffiASURETffiNT OF PARTICLES). [Pg.70]

Because of the much shorter wavelength of elecuon beams, the Ewald sphere becomes practically planar in elecU on diffraction, and diffraction spots are expected in this case which would only appear in X-ray diffraction if the specimen were rotated. [Pg.121]

Diffraction is usefiil whenever there is a distinct phase relationship between scattering units. The greater the order, the better defined are the diffraction features. For example, the reciprocal lattice of a 3D crystal is a set of points, because three Laue conditions have to be exactly satisfied. The diffraction pattern is a set of sharp spots. If disorder is introduced into the structure, the spots broaden and weaken. Two-dimensional structures give diffraction rods, because only two Laue conditions have to be satisfied. The diffraction pattern is again a set of sharp spots, because the Ewald sphere cuts these rods at precise places. Disorder in the plane broadens the rods and, hence, the diffraction spots in x and y. The existence of streaks, broad spots, and additional diffuse intensity in the pattern is a common... [Pg.259]

The three iridium complexes 72d, 72f and 72g were analyzed by X-ray diffraction. Unfortunately the iridium complex 72a, the most efficient in many reactions, failed to give suitable crystals for analysis but the corresponding crystalline rhodiiun complex 73 coifld be analyzed. According to the results obtained, the coordination sphere of the Ir atom and of the Rh atom can be described as pseudo-square planar (Fig. 12). [Pg.220]

The notion of a reciprocal lattice cirose from E vald who used a sphere to represent how the x-rays interact with any given lattice plane in three dimensioned space. He employed what is now called the Ewald Sphere to show how reciprocal space could be utilized to represent diffractions of x-rays by lattice planes. E vald originally rewrote the Bragg equation as ... [Pg.38]

An attempt has been made by Spiering et al. [39,40] to relate the magnitude of the interaction parameter F(x) as derived from experiment to the elastic interaction between HS and LS ions via an image pressure [47]. To this end, the metal atoms, inclusive of their immediate environments, in the HS and LS state are considered as incompressible spheres of radius /"h and Tl, respectively. The spheres are embedded in an homogeneous isotropic elastic medium, representing the crystal, which is characterized by specific values of the bulk modulus K and Poisson ratio a where 0 < a < 0.5. The change of molecular volume A Fas determined by X-ray diffraction may be related to the volume difference Ar = Ph — of the hard spheres by ... [Pg.65]

IR and Raman spectroscopy have been commonly used and, for example, the effects of pressure on the Raman spectrum of a zinc compound with a N2C12 coordination sphere around the metal, have been investigated.28 IR spectroscopy has been utilized in studies of the hydration of zinc in aqueous solution and in the hydrated perchlorate salt.29 Gas phase chemistry of zinc complexes has been studied with some gas phase electron diffraction structures including amide and dithiocarbamate compounds.30-32... [Pg.1150]


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