Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Difference equations substitution

A difference equation is a relation between the differences and the independent variable, A y, A " y,. . . , Ay, y, x) = 0, where ( ) is some given function. The general case in which the interval between the successive points is any real number h, instead of I, can be reduced to that with interval size I by the substitution x = hx. Hence all further difference-equation work will assume the interval size between successive points is I. [Pg.459]

Substitution If it is possible to rearrange a difference equation so that it takes the form af oy, o + hf 1 -1- cfy, = ( )(x) with a, b, c constants, then the substitution =fxyx reduces the equation to one with constant coefficients. [Pg.460]

Because the feed tray is essentially non-effective it is suggested that an additional theoretical tray be added to allow for this. This can be conveniently solved by the nomographs [21] of Figures 8-16 and 17. If the minimum number of trays in the rectifying section are needed, the)t can be calculated by the Fenske equation substituting the limits of xpi for x jj and x i, and the stripping section can be calculated by difference. [Pg.22]

STRATEGY If we know the mass loss, we can find the energy released by using Einstein s equation. Therefore, we must calculate the total mass of the particles on each side of the nuclear equation, take the difference, and substitute the mass difference into Eq. 6. Then we determine the number of nuclei in the sample from N = m(sample)/m(atom) and, finally, multiply the energy released from the fission of one nucleus bv that number to find the energy released by the sample. [Pg.837]

In order to develop a difference equation from (11), we substitute linear combinations of the values of u at the grid nodes in place of w and the integral with u that can be obtained through the interpolations in some neighborhood of the node x. The simplest interpolation gives... [Pg.152]

Constant Coefficient and Q(x) = O (Homogeneous) The solution is obtained by trying a solution of the form yx = tfix. When this trial solution is substituted in the difference equation, a polynomial of degree n results for (3. If the solutions of this polynomial are denoted... [Pg.35]

The phenol work has now been extended to a whole series of different alcohols which all have a very substantial number of bases which give rise to constant acid lines, i.e., a series of different — AH vs. Aron lines for different alcohols substituted phenols, 1,1,1,3,3,3 hexafluoro-2-propanol (CF3)2CHOH 81), t-butyl alcohol (52) and trifluoroethanol 83). In addition, the acid pyrrole 84) produced a similar correlation. To be sure, there are exceptions to these correlations, but a very wide range of donor t5 es conform, making the correlations quite general and valuable. The several correlations described above are plotted in Fig. 7, where they are indicated with solid lines. The equations for the straight lines ire given in Table 9. [Pg.132]

A-Substituted 5-amino-1,2,3,4-thiatriazoles (13) were obtained by Freund and Hempel in 1895 by treating thiosemicarbazides with nitrous acid (Equation (15)) <1895CB74>. This method has been used by others to prepare a number of different A-substituted 5-aminothiatriazoles (13) in good yields ( 80%) <81JIC1087>. [Pg.726]

Heating of 1,2,3-triazolium-l-aminide 168 with acrylonitrile in dry acetone at reflux yielded a mixture of pyrrolo[2,3-similar reactions with different N-substituted maleimides produced only one product in each case. Table 6 summarizes the results of these reactions <2001J(P1)1778>. [Pg.152]

Word problems often deal with how many of two or more coins, how many ducks and elephants, how much to invest in this or that, how many red and green jelly beans, and so on. You let variables represent the numbers of coins or ducks or dollars or jelly beans. When working with two different equations written about the same situation, then you have two different variables and need to do some algebra to knock that down to one equation. That s where substitution comes in. [Pg.229]

Now we are able to substitute B/t) in Eq. 8 from Eq. 9. After replacing the acceleration Rj (t) with the force F/ (t) we finally obtain Eq. 6. There are several others algorithms to integrate the equations of motion (e.g., leapfrog, Verlet). The consequences of different equation of motion integration schemes with regard to AMD are discussed in the excellent review of Remler and Madden (54). [Pg.116]

Substituting the expressions for differences Akyi, k = 1,2,..., m, one can modify it to an mth order linear difference equation related to an unknown y ... [Pg.3]

Isoprenoid acyclic polyene carbocations with 6, 14, and 18 tt-electrons were synthesized.138 Considering also previous data for carotenoid dications, an equation correlating /.max (ranging from 400 to 1100 nm) and the number of sp2 hybridized carbon atoms in the dication was developed. Dication (67) and an analogue with a different alkyl substitution pattern were prepared as PF6 salts.139 These dications form... [Pg.218]

This can be converted into the following difference equation by appropriate substitutions ... [Pg.714]

Thus we consider only the commutation relation [F3, V+] = oJ+ and apply it to the basis vectors jm. After some algebra involving the substitution of Eqs. (40a), (40b), and (31), we obtain a linear relationship among several of the jm. Since these basis vectors are linearly independent we set their coefficients equal to zero and the result is a pair of difference equations which must be satisfied by the coefficients aj and cy... [Pg.24]

The Neumann boundaries (which involve derivatives) are converted into finite difference form and substituted into the finite difference equations for the nodes in the specified region (e.g. above the electrode surface). The Dirichlet conditions (which fix the concentration value) may be substituted directly. [Pg.95]

This indeed is the most significant result of the Y-T analyses summarized in Table 16 (or 17). For the different a-substituted benzyl cations the linear relationship between Tq and alkene basicities AG(cc)h+ is described by equation (34)... [Pg.361]

In the case of LiCl, NaCl, and KC1, Figure 6 enables experimental values to be compared with theoretical ones calculated by the Fuoss equation, substituting for the a parameter the lowest value with a physical meaning (a = 2.413, the sum of Li+ and Cl" crystallographic radii), in order to get larger theoretical values for KA. As seen from Figures 5 and 6, the observed trends in almost the whole range of solvent composition are linear but with different slopes from the theoretical one in the... [Pg.96]

The substituted finite difference equations will contain the terms 0.000427A ... [Pg.1838]

After substituting the logarithmic-mean temperature difference. Equation 4.4.4, into Equation 4.4.14 we find that... [Pg.185]

Now substituting 1, 2, 3, and 4 for m results in these finite difference equations for the interior nodes ... [Pg.319]

Substituting this value of t and other quantities, the explicit finite difference Equations (a) and (b) reduce to... [Pg.337]

Again we did not use Ihe superscript i or / + 1 for quantities that do not change with time. The implicit method imposes no limit on the time step, and thus we can choose any value we want. However, we again choose At = 15 s. and thus r = 0.46875, to make a comparison with part (a) possible. Substituting this value of t and other given quantities, the two implicit finite difference equations developed here reduce to... [Pg.338]

Substituting this value of r and ottier given quantities, the developed transient, finite difference equations simplify to... [Pg.347]


See other pages where Difference equations substitution is mentioned: [Pg.137]    [Pg.459]    [Pg.3]    [Pg.88]    [Pg.188]    [Pg.35]    [Pg.241]    [Pg.240]    [Pg.88]    [Pg.188]    [Pg.149]    [Pg.431]    [Pg.138]    [Pg.304]    [Pg.218]    [Pg.137]    [Pg.68]    [Pg.25]    [Pg.92]    [Pg.286]    [Pg.1156]   


SEARCH



Difference equation

Equations substituting

© 2024 chempedia.info