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1,5-dienyl hydride shift

We have delineated the mechanism of this new diastereoselective reaction that involves an initial IMDA, followed by a double-bond isomerization, and finally 1,5-dienyl hydride shift [37]. The racemic tricycle carboxyhc acid was resolved via (S)-2-phenylglycinamide and converted to the aldehyde 46 that served as a convenient intermediate for analog synthesis. [Pg.562]

See other pages where 1,5-dienyl hydride shift is mentioned: [Pg.858]    [Pg.180]    [Pg.235]    [Pg.274]    [Pg.950]    [Pg.283]    [Pg.274]    [Pg.68]    [Pg.137]   
See also in sourсe #XX -- [ Pg.561 ]



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Dienyl

Hydride shift

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