Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Dienes aminomercuration-demercuration

There are several methods available for the electrophilic addition of hydrogen and nitrogen to alkenes, dienes and alkynes. While the direct electrophilic addition of amines to these substrates is not feasible, aminomercuration-demercuration affords a very useful indirect approach to such amines. The addition of amides to C—C multiple bonds can be effected directly through the Ritter reaction or by the less direct, but equally useful, amidomercuration-demercuration process using either nitriles or amides. Similarly, H—N3 addition to alkenes can be carried out directly or via mercuration to produce organic azides. [Pg.290]

Nonconjugated dienes also undergo aminomercuration-demercuration to generate pyrrolidines, piperidines and their heterocyclic analogs (equations 156-158).211-2,8... [Pg.291]


See other pages where Dienes aminomercuration-demercuration is mentioned: [Pg.636]    [Pg.19]   
See also in sourсe #XX -- [ Pg.291 ]

See also in sourсe #XX -- [ Pg.4 , Pg.291 ]

See also in sourсe #XX -- [ Pg.4 , Pg.291 ]




SEARCH



Aminomercuration

Aminomercuration demercuration

Demercuration

© 2024 chempedia.info