Nanoparticles dielectric

Although no quantum confinement should occur in the electronic energy level structure of lanthanides in nanoparticles because of the localized 4f electronic states, the optical spectrum and luminescence dynamics of an impurity ion in dielectric nanoparticles can be significantly modified through electron-phonon interaction. Confinement effects on electron-phonon interaction are primarily due to the effect that the phonon density of states (PDOS) in a nanocrystal is discrete and therefore the low-energy acoustic phonon modes are cut off. As a consequence of the PDOS modification, luminescence dynamics of optical centers in nanoparticles, particularly, the nonradiative relaxation of ions from the electronically excited states, are expected to behave differently from that in bulk materials. 

Eli Y2O3 nanolayers coated on different dielectric nanoparticles Recently, the structural and optical properties of Eu3+ Y2C>3 films coated on a variety of dielectric nanoparticles have been investigated using transmission electron microscope (TEM), X-rays diffraction (XRD) and site-selective laser spectroscopic methods (Chen, X.Y. et al., 2005 Chen et al., 2003a). Eu3+ ions are employed as probes for the study of crystallization and multi-site structure as well as the luminescent centers in nanolayers. It was found that the luminescent nanolayers exhibit distinct thermodynamics and luminescence properties. 

Figure 11. Trapping of nanoparticles inside a silicon Slot Waveguide. (a) SEM of 100 nm wide slot waveguide, (b-d) Demonstration of trapping and release of 75 nm dielectric nanoparticles from inside slot. These experiments were conducted with approximate 100 mW of excitation power at 1,550 nm.

Lanthanides location—are they inside or outside 136 6.1.2. Eu Y203 nanolayers coated on different dielectric nanoparticles 152... 

Pukhov KK, Basiev TT, Orlovskii YV (2008) Spontaneous emission in dielectric nanoparticles. JETP Lett 88 12-18... 

The optical properties of metal nanoparticles have traditionally relied on Mie tlieory, a purely classical electromagnetic scattering tlieory for particles witli known dielectrics [172]. For particles whose size is comparable to or larger tlian tire wavelengtli of the incident radiation, tliis calculation is ratlier cumbersome. However, if tire scatterers are smaller tlian -10% of tire wavelengtli, as in nearly all nanocrystals, tire lowest-order tenn of Mie tlieory is sufficient to describe tire absorjDtion and scattering of radiation. In tliis limit, tire absorjDtion is detennined solely by tire frequency-dependent dielectric function of tire metal particles and the dielectric of tire background matrix in which tliey are... 

Figure C2.17.13. A model calculation of the optical absorjDtion of gold nanocrystals. The fonnalism outlined in the text is used to calculate the absorjDtion cross section of bulk gold (solid curve) and of gold nanoparticles of 3 mn (long dashes), 2 mn (short dashes) and 1 mn (dots) radius. The bulk dielectric properties are obtained from a cubic spline fit to the data of [237]. The small blue shift and substantial broadening which result from the mean free path limitation are...

Stella A ef al 1996 Comparative study of thermodynamic properties of metallic and semiconducting nanoparticles in a dielectric matrix Mater. Res. Soc. Symp. Proc. 400 161... 

When the silver nanocrystals are organized in a 2D superlattice, the plasmon peak is shifted toward an energy lower than that obtained in solution (Fig. 6). The covered support is washed with hexane, and the nanoparticles are dispersed again in the solvent. The absorption spectrum of the latter solution is similar to that used to cover the support (free particles in hexane). This clearly indicates that the shift in the absorption spectrum of nanosized silver particles is due to their self-organization on the support. The bandwidth of the plasmon peak (1.3 eV) obtained after deposition is larger than that in solution (0.9 eV). This can be attributed to a change in the dielectric constant of the composite medium. Similar behavior is observed for various nanocrystal sizes (from 3 to 8 nm). 

Kelly, K.L., Coronado, E., Zhao, L.L. and Schatz, G.C. (2003) The optical properties of metal nanoparticles the influence of size, shape, and dielectric environment. The Journal of Physical Chemistry B, 107, 668-677. 

In this Section we want to present one of the fingerprints of noble-metal cluster formation, that is the development of a well-defined absorption band in the visible or near UV spectrum which is called the surface plasma resonance (SPR) absorption. SPR is typical of s-type metals like noble and alkali metals and it is due to a collective excitation of the delocalized conduction electrons confined within the cluster volume [15]. The theory developed by G. Mie in 1908 [22], for spherical non-interacting nanoparticles of radius R embedded in a non-absorbing medium with dielectric constant s i (i.e. with a refractive index n = Sm ) gives the extinction cross-section a(o),R) in the dipolar approximation as ... 

Bragg mirrors on periodic stacks of layers Periodic stacks of metal nanoparticles or dielectric layers with alternating high and low refractive index produce a desired reflectance of the mirror that depends on the thickness and the refractive index of the layers in the stack 16,17... 

Cassagneau, T. and Caruso, F., Continuous silver nanoparticle coatings on dielectric spheres, Adv. 

---