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1.1- Dichloro-1-nitropropane

Dinitro-2-butene may be prepared from 1-chloro-l-nitro-ethane by the same procedure, in 30% yield. The compound melts at 28-28.5° and has a boiling point of 135°/11 mm. Commercially available 1-chloro-l-nitroethane contains about 10% 1,1-dichloro-l-nitro-ethane and 2-chloro-2-nitropropane which cannot be separated by distillation, but these impurities do not interfere with the preparation. Distillation of 2,3-dinitro-2-butene behind safety glass in a nitrogen atmosphere is advisable. The submitters, in preparing this compound, have had one explosion over a period of ten years. [Pg.71]

EINECS 203-468-6, see Ethylenediamine EINECS 203-470-7, see Allyl alcohol EINECS 203-472-8, see Chloroacetaldehyde EINECS 203-481-7, see Methyl formate EINECS 203-523-4, see 2-Methylpentane EINECS 203-528-1, see 2-Pentanone EINECS 203-544-9, see 1-Nitropropane EINECS 203-545-4, see Vinyl acetate EINECS 203-548-0, see 2,4-Dimethylpentane EINECS 203-550-1, see 4-Methyl-2-pentanone EINECS 203-558-5, see Diisopropylamine EINECS 203-560-6, see Isopropyl ether EINECS 203-561-1, see Isopropyl acetate EINECS 203-564-8, see Acetic anhydride EINECS 203-571-6, see Maleic anhydride EINECS 203-576-3, see m-Xylene EINECS 203-598-3, see Bis(2-chloroisopropyl) ether EINECS 203-604-4, see 1,3,5-Trimethylbenzene EINECS 203-608-6, see 1,3,5-Trichlorobenzene EINECS 203-620-1, see Diisobutyl ketone EINECS 203-621-7, see sec-Hexyl acetate EINECS 203-623-8, see Bromobenzene EINECS 203-624-3, see Methylcyclohexane EINECS 203-625-9, see Toluene EINECS 203-628-5, see Chlorobenzene EINECS 203-630-6, see Cyclohexanol EINECS 203-632-7, see Phenol EINECS 203-686-1, see Propyl acetate EINECS 203-692-4, see Pentane EINECS 203-694-5, see 1-Pentene EINECS 203-695-0, see cis-2-Pentene EINECS 203-699-2, see Butylamine EINECS 203-713-7, see Methyl cellosolve EINECS 203-714-2, see Methylal EINECS 203-716-3, see Diethylamine EINECS 203-721-0, see Ethyl formate EINECS 203-726-8, see Tetrahydrofuran EINECS 203-729-4, see Thiophene EINECS 203-767-1, see 2-Heptanone EINECS 203-772-9, see Methyl cellosolve acetate EINECS 203-777-6, see Hexane EINECS 203-799-6, see 2-Chloroethyl vinyl ether EINECS 203-804-1, see 2-Ethoxyethanol EINECS 203-806-2, see Cyclohexane EINECS 203-807-8, see Cyclohexene EINECS 203-809-9, see Pyridine EINECS 203-815-1, see Morpholine EINECS 203-839-2, see 2-Ethoxyethyl acetate EINECS 203-870-1, see Bis(2-chloroethyl) ether EINECS 203-892-1, see Octane EINECS 203-893-7, see 1-Octene EINECS 203-905-0, see 2-Butoxyethanol EINECS 203-913-4, see Nonane EINECS 203-920-2, see Bis(2-chloroethoxy)methane EINECS 203-967-9, see Dodecane EINECS 204-066-3, see 2-Methylpropene EINECS 204-112-2, see Triphenyl phosphate EINECS 204-211-0, see Bis(2-ethylhexyl) phthalate EINECS 204-258-7, see l,3-Dichloro-5,5-dimethylhydantoin... [Pg.1482]

It has been proposed that 8-aminodcoxyguanosinc is formed from the nitronate tautomer of 2-nitropropane either by base nitrosation followed by reduction, or via an enzyme-mediated conversion of the nitronate anion to hydroxyiam ine-O-sulfonate or acetate, which yields the highly reactive nitrenium ion NHj (Sodum et al., 1993). Sodum et al. (1994) have provided evidence for the activation of 2-nitropropane to an aminating species by rat liver aryl sulfotransferase in vitro and in vivo. Pretreatment of rats with the aryl sulfotransferase inhibitors pentachlorophenol or 2,6-dichloro-4-nitrophenol significantly decreased the levels of nucleic acid modifications produced in the liver by 2-nitropropane treatment. Partially purified rat liver aryl sulfotransferase activated 2-nitropropane and its nitronate at neutral pH to a reactive species that aminated guanosine at the position. This activation was dependent on the presence of the enzyme, its specific cofactor adenosine 3 -phosphate 5 -phosphosulfate, and mercaptoethanol. It was inhibited... [Pg.1089]

Bromo-2-nitropropane-1,3-diol 2-n-Octyl-4-isothiazolin-3-one 10,10-Oxybisphenoxyarsine Sodium o-phenylphenate Zinc pyrithione antimicrobial, latex coatings p-Chloro-m-cresol antimicrobial, latex emulsions Quaternium-15 Tribromosalicylanilide antimicrobial, latex paints 4,5-Dichloro-2-n-octyl-4-isothiazolin-3-one antimicrobial, laundry prods. [Pg.4830]


See other pages where 1.1- Dichloro-1-nitropropane is mentioned: [Pg.416]    [Pg.2312]    [Pg.309]    [Pg.310]    [Pg.2481]    [Pg.297]    [Pg.308]    [Pg.349]    [Pg.1258]    [Pg.349]    [Pg.532]    [Pg.416]    [Pg.601]    [Pg.601]    [Pg.218]    [Pg.349]    [Pg.67]    [Pg.281]    [Pg.273]    [Pg.2312]    [Pg.4828]    [Pg.5688]    [Pg.85]    [Pg.249]    [Pg.260]    [Pg.309]    [Pg.310]    [Pg.297]    [Pg.2481]    [Pg.297]    [Pg.308]    [Pg.273]    [Pg.227]   
See also in sourсe #XX -- [ Pg.294 ]




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Nitropropanes

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