1.2- Diamino-3-phenyl

Bis(benzodiazepinyl) methanes have been made from bis-(3,4-diamino-phenyl)methane and 1,3-diketones (74RZC1073). 

Hydrazin 2-Benzy 1-1-(2,4-diamino-phenyl)- El6a, 608 (Hydrazon-Red.)... 

Chiral Reagent The diamino phenyl borane (6) derived from (15,25)-l,2-diaminocyclohexane has been used as a chiral proton source for the enantioselective protonation of prochiral cyclic lithium enolates, with ee s up to 93% (eq 9). (15,25)-1,2-Dia-minocyclohexane proved to be highly superior to 1,2-diphenyl ethylenediamine or bis-naphthylamine. 

Bis-f 2-amino-phenyl]- 688 Bis-f4-amino-phenyl]- 516 Bis- 3,4-diamino-phenyl]- 516 Bis- [ 4-nitro- 3-amino-ph enyl ]- 516 Bis-[2-nitro-phcnyl]- 688, 732 Bis-[4-nitro-phenyl]- 516 Dinaphthyl-(2)- 666 Diphenyl- 661... 

Amino-1-methyl- 536 l-(2,4-Diamino-phenyl)- 534 l-(2,4-Dinitro-phenyl)- 534 4-Methyl- 690 4-Nitro- 1-methyl- 536 l-(2-Nitro-phcnyl)- 608... 

The successful application of simple bis(naphthalic anhydrides) containing oxy-, keto- and sulfo-groups, i.e. oxy-bis(4,5-dicarboxynaphthyl-l), keto-bis(4,5-dicarboxynaphthyl-1) and sulfone-bis(4,5-dicarboxynaphthyl-l), was reported in Refs. [177-180] 3,3, 4,4 -tetraaminodiphenyl oxide and 2,2-bis(3,4-diamino-phenyl) hexafluoropropane were used as monomers ... 

HFDA-I- DAPE (diamino-phenyl ether), 30% aluminum powder... 

CuHgiNgl Verbindniig CggHaNgOi ana [z-(2.4-Diamino-phenyl). aoetoaoety 1]-[K-(2.4-diamiiio-phenyl).aoatea8ig8 uie]-athyleator 14, 657. 

Holmes-Smith AS, Zheng X, Uttamlal M (2006) Characterization of an electropolymerized Pt(II) diamino phenyl porphyrin polymer suitable for oxygen sensing. Meas Sci Technol... 

Of the classical Hofmann, Curtius, Lossen and Schmidt degradations, only a rare example of the first is known, hypobromite converting 4,7-diamino-2-phenyl-6-pteridinecar-boxamide (208) into 8-amino-2,3-dihydro-6-phenyl-l//-imidazo[4,5-g]pteridin-2-one (209 equation 64) (63JOC1203). 

Imidazole, 1,2-diamino-4-phenyl-oxidation, S, 440, 454 Imidazole, 4,5-diaryl-synthesis, S, 481 Imidazole, diazoreactions, S, 96... 

Isoxazole, 3-chloro-5-hydroxymethyl-oxidation, 6, 27 Isoxazole, 4-chloromethyI-reactions, 6, 53 Isoxazole, 5-chloro-3-phenyl-reactions, 6, 58 Isoxazole, 3-cyano-reactions, 6, 30 Isoxazole, diacyl-synthesis, 6, 79 Isoxazole, 3,4-dialkyl-synthesis, 6, 83 Isoxazole, 3,5-dialkyl-synthesis, 6, 83 Isoxazole, 4,5-dialkyl-synthesis, 6, 83 Isoxazole, 3,5-diamino-2-amino-l-azirines from, 7, 89 Isoxazole, 3,5-diaryl-synthesis, 6, 63 Isoxazole, 2,5-dihydro-synthesis, 6, 79 Isoxazole, 4,5-dihydro-dehydrogenation, 6, 4... 

Pyrimido[5,4-d]pyrimidine, 6,8-diamino-4-hydroxy-2-phenyl-synthesis, 3, 364... 

Attempted dehydrocyclization of the 6-acylhydrazinopyrimidine 65 by heating with polyphosphoric acid led, instead, to pyrimidine ring rupture, yielding the l,l-diamino-2-nitro-2-(3-phenyl-l,2,4-triazol-5-yl)ethene 66. Cyclocondensation of the latter with triethyl orthoformate gave the fully aromatic triazolopyrimidine 67 (94JHC1171) (Scheme 23). 

Fragmentary ultraviolet spectral data are available for 3-amino-1,2,4-triazole. Early chemical data on 3,5-diamino-2-phenyl-l,2,4-triazole were interpreted on the basis of the diimino structure 201, but ultraviolet spectral evidence was later stated to favor either structure 202 or 203. ... 

R2 = C6H5 3-Amino-l-phenyl-propen R2 = CN /,4-Diamino-buten-(2)... 

Pentafluor-I-amino-3-imino- 611, 616 Pentafluor-1,3-diamino- 611,616 Phenyl- 285... 

Chlor-2,4-diamino- -1-oxid 502 6-Chlor-4-dichlormethyl-2-phenyl- 618 6-Chlor-4-mcthoxy-2-phenyl- 595 6-Chlor-4-methyl-2-phcnyl- 595 6-Chlor-4-trichlormethyl-2-phenyl- 618... 

C 4H gN404 37389-83-6) see Trimethoprim 5-[[3,5-diamino-4-(4-methoxyphenoxy)phenyl]methyl]-5-methyl-2,4-imidazolidinedione (C sH2oN404 5165-04-8) see Etiroxate... 

Figure 6-11. 1 -H-Benzotriazole, 2,5-bis(N-pyridyl)-1,3,4-oxadiazole, cyclohexylammonium benzoate, benzylsulfonylacetic acid, 2,4-diamino-6-mercapto pyrimidine, hydroxamic acid, 3-phenyl-2-propyn-1-ol, dicyclopentadiene dicarboxylic acid.

---