Detection aerosol-based

In the past, aerosol-based detection methods such as evaporative light scattering detection (ELSD), condensation nucleation light scattering detection... 

Some APIs and most counterions laclc or have only a weak chromophore, so that absorbance detectors cannot be used. At present, such analytes are typically detected by aerosol-based detection techniques such as evaporative light scattering and charged aerosol detection. Both detection techniques have already been described in Section 8.3. CAD has been shown to overcome many of the issues found with ELSD. CAD is more sensitive, has a wider dynamic range and better precision, and, although response is nonlinear, calibration is less complex than with ELSD. 

A better field test for explosives is Exspray. Expray is a unique, aerosol-based explosive detection system field test kit for the explosives detection and... 

One is compelled to pose the question if experimentally it will become possible to decide whether the 14C variations observed on tree-ring samples, peat bogs, sediments, etc., are primarily caused by an external forcing of the system (production rate variations) or by an internal one. Recent progress in detection of small numbers of nuclei of an isotope by mass spectrometry based on the use of a particle accelerator [57,58] make it possible to measure the cosmic ray produced 10Be or 36C1 deposited in only 1 kg of ice. These isotopes get attached to aerosol particles and deposited with them. 

The analytic principles that have been applied to accumulate air quality data are colorimetry, amperometry, chemiluminescence, and ultraviolet absorption. Calorimetric and amperometric continuous analyzers that use wet chemical techniques (reagent solutions) have been in use as ambient-air monitors for many years. Chemiluminescent analyzers, which measure the amount of chemiluminescence produced when ozone reacts with a gas or solid, were developed to provide a specific and sensitive analysis for ozone and have also been field-tested. Ultraviolet-absorption analyzers are based on a physical detection principle, the absorption of ultraviolet radiation by a substance. They do not use chemical reagents, gases, or solids in their operation and have only recently been field-tested. Ultraviolet-absorption analyzers are ideal as transfer standards, but, as discussed earlier, they have limitations as air monitors, because aerosols, mercury vapor, and some hydrocarbons could, interfere with the accuracy of ozone measurements made in polluted air. 

Elemental mass distribution - The aerosol sampled by the LPI for elemental analysis was impacted on coated mylar films affixed to 25 mm glass discs. The mylar had been coated with Apiezon L vacuum grease to prevent particle bound. The LPI samples were sent to Crocker Nuclear Laboratory for elemental analysis by PIXE using a focused alpha particle beam of 3 to 4 mm diameter. Nanogram sensitivities for most elements were achieved with the focused beam. A detailed description of the PIXE focused beam technique applied to LPI samples can be found in Ouimette (13). Based upon repeated measurements of field samples, the estimated measurement error was about 15-20% or twice the minimum detection limit, whichever was larger. 

Continuous Sampling and Determination. There are no truly continuous techniques for the direct determination of sulfuric acid or other strong acid species in atmospheric aerosols. The closest candidate method is a further modification of the sensitivity-enhanced, flame photometric detector, in which two detectors are used, one with a room-temperature de-nuder and one with a denuder tube heated to about 120 °C. Sulfuric acid is potentially determined as the difference between the two channels. In fact, a device based on this approach did not perform well in ambient air sampling (Tanner and Springston, unpublished data, 1990). Even with the SF6-doped H.2 fuel gas for enhanced sensitivity, the limit of detection is unsuitably high (5 xg/m3 or greater) because of the difficulty in calibrating the two separate FPD channels with aerosol sulfates. 

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