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Desymmetrization and Enzymatic Strategies for Chiral Propargyl Alcohol Synthesis

4 DESYMMETRIZATION AND ENZYMATIC STRATEGIES FOR CHIRAL PROPARGYL ALCOHOL SYNTHESIS [Pg.155]

Similar efforts were successful with lyophilized bakers yeast and e.e. values were up to 97%. Propargylic ketones were reduced to chiral alcohols under anaerobic conditions using Geotrichum candidum (to get both R and S isomers based on substitution), and Aspergillus niger (/ -isomer) or Mortierella isabellina (S-isomer) for obtaining the [Pg.156]



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Alcohols chiral

Alcohols chiral synthesis

Alcohols desymmetrizations

Alcohols synthesis

Chiral synthesis

Desymmetrization

Desymmetrization enzymatic

Propargyl alcohol

Propargylic alcohols

Propargylic alcohols, chiral

Strategy for synthesis

Synthesis chiral propargylic alcohol

Synthesis strategies

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