Desiccants selection

Desiccants. A soHd desiccant is simply an adsorbent which has a high affinity and capacity for adsorption of moisture so that it can be used for selective adsorption of moisture from a gas (or Hquid) stream. The main requkements for an efficient desiccant are therefore a highly polar surface and a high specific area (small pores). The most widely used desiccants (qv) are siHca gel, activated alumina, and the aluminum rich zeoHtes (4A or 13X). The equiHbrium adsorption isotherms for moisture on these materials have characteristically different shapes (Fig. 3), making them suitable for different appHcations. 

However, low velocities require towers with large cross-sectional areas to handle a given gas flow, and allow the wet gas to channel through the desiccant bed and not be properly dehydrated. In selecting the design velocity therefore, a compromise must be made between the tower diameter and the maximum use of the desiccant. Figure 8-22 shows a maximum design velocity. Smaller velocities may be required due to pressure drop considerations. 

Refrigerant temperatures greater than 32°F suggest the steam jet or lithium bromide absorption system. Between 30°F and —40°F, the ammonia-water absorption or a mechanical compression system is indicated. At less than —40°F, a mechanical compression is used, except in special desiccant situations. The economics of temperature level selection will depend on utility (steam, power) costs at the point of installation and the type of pay-out required, because in some tonnage ranges, the various systems are competitive based on first costs. 

Fig. 1. A general, simplified and self-explanatory layout of the wheat breeding programme at the Volcani Center, Israel. The selection for drought resistance is affected at about the F4 and later generations, by using infra-red thermometry, chemical desiccation and yield under stress. A summer (off-season) nursery is incorporated as means for selection for heat tolerance.

This complex, formerly called pyridine perchromate and now finding application as a powerful and selective oxidant, is violently explosive when dry [1], Use while moist on the day of preparation and destroy any surplus with dilute alkali [2], Preparation and use of the reagent have been detailed further [3], The analogous complexes with aniline, piperidine and quinoline may be similarly hazardous [4], The damage caused by a 1 g sample of the pyridine complex exploding during desiccation on a warm day was extensive. Desiccation of the aniline complex had to be at ice temperature to avoid violent explosion [4]. Pyridinium chlorochromate is commercially available as a safer alternative oxidant of alcohols to aldehydes [5], See Chromium trioxide Pyridine Dipyridinium dichromate See Other AMMINECHROMIUM PEROXOCOMPLEXES... 

Selecting the Right Desiccant. http //www.multisorb.com/faqs/selecting.html... 

Hubbard and Miller87 used a Lewis acid catalyzed Diels-Alder reaction between y.y-disubstituted o. /i-unsaluralcd esters and cyclopentadiene in their approach toward oligomeric cyclopentanoids. In order for the reaction to proceed, they needed to add trimethylaluminum as a desiccant prior to addition of the Lewis acid catalyst aluminum trichloride. The endo/exo selectivity of the reaction with 97, depicted in equation 29, increased from 98/99 = 75/25 to 88/12 when the reaction temperature was dropped from room temperature to —20 °C. 

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