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Deliberate distribution function

Patterned SAMs are composed of two or more SAMs which are deliberately distributed on specific areas on the surface. They can be fabricated in different ways including microcontact printing and dip-pen nanolithography. Patterned SAMs have been used to attract particular nanostructures like ribbons or wires to particular areas on the surface. They have also been used in the functionalization of biosensors in which the localized SAMs have an affinity for specific cells and proteins. Crystallization on patterned SAMs where the crystals grow in localized areas has also been demonstrated. [Pg.49]

The bulk phases are the similar regions of the system with homogeneous distribution functions. Therefore, the independent factors v v can be deliberately given in symmetrical form, if two conditions are satisfied. Firstly, according to Eq. (3), for the excess volume... [Pg.146]

Clark et al. (40) developed what is a mathematically similar approach to Theil s, which was applied to both DPIs and pMDIs plus spacer and chambers. (Clark et al. deliberately avoided using data from pMDIs alone because of the difficulties associated with the ballistic nature of the plume.) The basis of the technique is the assumption that lung deposition is simply the inhaled dose minus that deposited in mouth and oropharynx. This approach does not require the application of a lung deposition model and is justified for most DPIs and pMDI since the fractions exhaled after a typical 5- to 10-s breath-hold are always close to zero. As an oral deposition function, Clark et al. chose to use the function proposed by Stahlhofen et al. and Rudolf et al., which is then numerically integrated with the size distribution derived from cascade impactor data to calculate oral deposition. Subtracting oral deposition from the inhaled dose allows calculation of the lung dose. Clark used gamma camera data from seven clinical studies, four DPI and three pMDI, to evaluate the approach. On analysis, it was seen that... [Pg.134]

Polyphosphazenes are inorganic polymers with properties and applicability that can be varied within exceptionally wide ranges with the functional substituent groups attached to the phosphorus atoms in their —P=N— chains. In general, the structure of a polymer is determined by the precursor monomer, and its properties are more the result of the statistical size distribution than of deliberate... [Pg.106]

Functionality refers to the moieties chemically distinct from the repeating units of polymer chains. It can be the terminal groups at chain ends or the functional groups deliberately added to a polymer chain. Determination of functionality type distribution of reactive oligomers (telechelics) is an old problem in polymer characterization. The classical method is the combination of SEC separation and functionality sensitive detection. Recent advances of the detection methods such as FT-NMR and MALDl-TOF MS have brought about big improvements in the precision of functionality characterization [12]. [Pg.46]

OT A, B eW " and C e R" " e R and iw e L The same algebraic syntax can be used to define thermodynamic frameworks as well, but what really counts in this context is the operator precedence > > - -, and not the original operator behavior. In fact, to stress that we do not talk about a true mathematical algebra, the operators are deliberately given new fancy names Chain (-F), Patch ( ) and Tell ( ) in order to avoid confusion with their arithmetic counterparts. Using these operators a thermodynamic function can be realized as a node in a coimected acyclic graph (tree). The -f- operator is both commutative and associative while the + operator is associative and distributive ... [Pg.666]


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