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D,L-3-Hydroxy-N-methyl-morphinan

D,L-3-Hydroxy-N-methyl-morphinan Phenyl trimethyl ammonium chloride D-Tartaric acid... [Pg.461]

The methylation of 51.4 parts by weight of D,L-3-hydroxy-N-methyl-morphinan is carried out with a methylating solution obtained from 51.5 parts by weight of phenyl-trimethyl-ammonium-chloride. The D,L-3-methoxy-N-methyl-morphinan is isolated in the form of its hydrobromide, which melts with 1 mol of water at 92°-94°C, without water at 239°-240°C. The base isolated from the aqueous solution by means of sodium carbonate melts at 81°-83 C. [Pg.461]


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1 -Hydroxy-2-methyl-l -

D,L-3-Hydroxy

Morphinane

Morphinanes

Morphinans

Morphinans, 63-hydroxy

N-methyl morphinan

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