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Cyclopentanone monooxygenase

Cyclohexanone and Cyclopentanone Monooxygenases as Baeyer-Villigerases and Sulfoxidation Catalysts... [Pg.48]

Figure 3 Illustration of overlapping substrate specificities of four BVMOs. Cyclohexanone monooxygenase (CHMO), cyclopentanone monooxygenase (CPMO), 4-hydroxyacetophenone monooxygenase (HAPMO) and phenylacetone monooxygenase (PAMO). For each enzyme, several typical substrates are... Figure 3 Illustration of overlapping substrate specificities of four BVMOs. Cyclohexanone monooxygenase (CHMO), cyclopentanone monooxygenase (CPMO), 4-hydroxyacetophenone monooxygenase (HAPMO) and phenylacetone monooxygenase (PAMO). For each enzyme, several typical substrates are...
Cyclohexanone and cyclopentanone monooxygenases have been used in the microbial BV oxidation of prochiral bicycloketones. A significant difference in behaviour of [3.3.0] and [4.3.0] substrates has been analysed by high-level DFT calculations.345 Al-BINOL complexes catalyse the enantioselective BV oxidation of cyclobutanones to give the corresponding y-butyrolactones in up to 84% ee.346 Advances in the enantioselective metal-catalysed reaction have been reviewed, especially for lactone preparation.347... [Pg.43]

More recently, the formal total syntheses of some bioactive natural products bearing a tetrahydrofurane moiety were achieved by enzymatic Baeyer-Villiger oxidation using cyclopentanone monooxygenases (CPMOs) from Comamonas sp. [Pg.24]

Cyclopentanone monooxygenase Pseudomonas NCIMB 9872 1 3-4 identical subunits NADPH 200 (54-58 each) 1 FAD per subunit 7.7 [48]... [Pg.1215]

See other pages where Cyclopentanone monooxygenase is mentioned: [Pg.52]    [Pg.244]    [Pg.244]    [Pg.111]    [Pg.114]    [Pg.337]    [Pg.344]    [Pg.256]    [Pg.69]    [Pg.344]    [Pg.256]    [Pg.1214]    [Pg.1228]    [Pg.1481]    [Pg.1481]    [Pg.61]    [Pg.360]    [Pg.60]    [Pg.154]   
See also in sourсe #XX -- [ Pg.1214 ]



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Cyclopentanone

Cyclopentanone monooxygenase (CPMO

Cyclopentanone monooxygenases

Cyclopentanone monooxygenases

Cyclopentanone monooxygenases CPMOs)

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Monooxygenases cyclopentanone monooxygenase

Monooxygenases cyclopentanone monooxygenase

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