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Cyclopentadienyl ligand interactions with metal center

The mechanism of the catalytic dehydrogenation appears to involve the cleavage of the Si-H bonds which is activated by the catalyst [19-20]. It has been proposed by Tilley that the active catalytic species is a metal hydride of the type L M-H (where L is the other ligand or ligands such as cyclopentadienyl or pentamethylcyclopentadienyl that are present on the metal). The metal hydride interacts with a compound containing a Si-H bond to generate a four-centered transition state (see Eq.7.11)... [Pg.266]

See other pages where Cyclopentadienyl ligand interactions with metal center is mentioned: [Pg.184]    [Pg.121]    [Pg.15]    [Pg.757]    [Pg.168]    [Pg.140]    [Pg.154]    [Pg.298]    [Pg.161]    [Pg.93]    [Pg.21]    [Pg.446]    [Pg.68]    [Pg.916]    [Pg.221]    [Pg.172]    [Pg.7]    [Pg.164]    [Pg.158]    [Pg.169]    [Pg.3101]    [Pg.54]    [Pg.67]    [Pg.65]    [Pg.245]    [Pg.446]    [Pg.282]    [Pg.7]    [Pg.66]    [Pg.139]    [Pg.3100]    [Pg.788]    [Pg.93]    [Pg.269]    [Pg.459]    [Pg.129]    [Pg.174]    [Pg.704]    [Pg.370]    [Pg.95]    [Pg.439]    [Pg.169]    [Pg.85]    [Pg.283]    [Pg.56]    [Pg.585]    [Pg.28]    [Pg.66]    [Pg.447]    [Pg.446]   
See also in sourсe #XX -- [ Pg.432 ]



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Interactions centers

Ligand interactions

Metal center

Metal-ligand interactions

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