Cyclooctadienes ring-opening metathesis polymerization

II), on a mesoporous support having a hexagonal unit cell. The catalyst was used to prepare 5-norbomene and cyclooctadiene copolymers by ring-opening metathesis polymerization. 

The complex is also active in ring-opening metathesis polymerization of 1,5-cyclooctadiene (COD), where the ruthenium—carbene bond is now the initiating point. Therefore, a mixture of MMA and COD undergoes a dual or tandem living polymerization of both monomers to generate block copolymers of COD and MMA, which can be converted into ethylene-block-MMA copolymers on subsequent hydrogenation, also catalyzed by the complex. 

For the ring-opening metathesis polymerization (ROMP) in heterophase [81], a water-soluble ruthenium alkylidene was employed for the emulsion polymerization of norbornene, and an oil-soluble catalyst for the miniemulsion polymerization of norbornene and 1,5-cyclooctadiene. Similar to the polymerization of ethylene in heterophase, an organic solution of the catalyst was first miniemulsified in water, after which the monomer was added to the miniemulsion. This resulted in a high monomer conversion for norbornene ( up to 97%), and a particle size of 250nm. 

The partial hydrogenation of multiple bonds includes chemical reactions of industrial interest for example, the partial hydrogenation of benzene to cyclohexene used to synthesize several compounds, from which the main is nylon production, the partial hydrogenation of 1,5-cyclooctadiene (COD) to cyclooctene (COE), which is an important industrial intermediate product for manufacturing special polymers such as poly-octenamers via ring-opening metathesis polymerization, which is used as a modifier in mbbers and thermoplastics (Sato, Aoki, Noyori, 1998 Rylander, 1985 Schmidt Schomacker, 2007). 

The catalysts 4a-d show no activity at room temperature but are stable for months in solution. We tested their activity in the ring-opening metathesis polymerization (ROMP) of 1,5-cyclooctadiene (COD) at 90°C in toluene-d8 (Figure 2). The Schiffbase catalysts 4a-d and 5c are clearly less active than... 

Feng J, Stoddart SS, Kanchana A, Weerakoon Chen KAW (2007) An efficient approach to surface-initiated ring-opening metathesis polymerization of cyclooctadiene. Langmuir... 

As shown by reaction 7.2.3, dimerization of butadiene is used for the selective formation of 1,5-cyclooctadiene (1,5-COD), which on selective hydrogenation gives cyclooctene. By ring-opening metathesis polymerization (ROMP) of cyclooctene, a specialty polymer called Vestenamer is manufactured (see Section 7.3.1). 

Opstal, T., Couchez, K., Verpoort, F., Easily acessible ring opening metathesis and atom transfer radical polymerization eatalysts based on arene, norbomadiene and cyclooctadiene ruthenium eomplexes bearing Schiff base ligands, Adv. Synth. Catal. 2003,345 393—401. 

A type of ring opening addition polymerization using transition metal catalysts not unlike Ziegler-Natta catalysts is called metathesis polymerization." Metathesis polymers, first made in the 1960s, are called polyalkenamers. Polymers made from cyclooctadiene and norbornadiene have applications as specialty elastomers. The polymerization of norbornadiene can be summarized as follows ... 

The presence of halogen atoms appears to exert little, if any, effect on catalyst activity, but it can influence the course of the metathesis reaction. Vinylic halides are unreactive, as exemplified by the ring-opening polymerization of l-chloro-l,5-cyclooctadiene, which afforded a perfectly alternating copolymer of butadiene and chloroprene (7/2) via polymerization exclusively through the unsubstituted double bond. 

Another example is ring-opening olefin metathesis polymerization (ROMP), as can be used for synthesis of polybutadiene from 1,5-cyclooctadiene. 

Ci6j C24/C16, C28/C16 and C32/C16 are essentially constant throughout the ring opening polymerization. The constancy of the C12/C16 ratio is especially significant in this respect, since the pairwise mechanism would have required cross metathesis of the cyclooctadiene and cyclobutene, which is unUkely [33]. 

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