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2-Cyanobenzyl cyanide

Cuitius rearrangement, 564 2-Cyanobenzyl cyanide, 541 Cyanoboration, 535-536 1-Cyanocyclopropanecarboxylic acid, 42 Cyanogen bromide, 148-149... [Pg.371]

SYNS ACETONITRILE, BENZOYLPHENYL- BENZ-ENEPROPANENITRILE, p-OXO-a-PHENYL-(9CI) a-BENZOYLBENZYL CYANIDE BENZOYLPHENYL-ACETONTTRILE a-BENZOYLPHENYLACETONITR-ILE a-CYANOBENZYL PHENYL KETONE a-CYANODEOXYBENZOIN... [Pg.1058]

Halogen atoms in the alpha position to an aromatic nucleus (benzyl-type) are very readily hydrolyzed. With proper precautions hydrolysis of the halogen atom of -cyanobenzyl chloride is possible without affecting the cyanide group -cyanobenzyl alcohol is obtained in 85% yield. ... [Pg.537]

On boiling bromobenzyl cyanide with an aqueous-alcoholic solution of sodium thiosulphate, the sodium salt of cyanobenzyl thiosulphuric acid is formed ... [Pg.199]

Diethyl (a-cyanobenzyl)malonate 118 Diethyl benzylidenemalonate (24.5 g) is dissolved in ethanol (250 ml), and a solution of potassium cyanide (6.5 g) in water (100 ml) is added. To the resulting clear liquid, 30% hydrochloric acid (11 g), diluted with water (50 ml), is added gradually and with cooling. The mixture is set aside for some days. Then the weakly acidic liquid, which barely smells of hydrogen cyanide, is treated with sufficient water to cause incipient turbidity. After 24 h a considerable yield of condensation product has separated as needles, which, when collected and washed with ethanol, melt at 48.5°. [Pg.867]

The products were the 3>4-acetals with retention of the 1,2-carbonyl groups. The reagent system trimethylsilyl cyanide-boron trifluoride etherate reacts with methyl 2,3-anhydro-4,6-0-benzylidene-ot-D-allopyranoside to yield the i><-cyanobenzyl ether (9) No epoxide... [Pg.66]

See other pages where 2-Cyanobenzyl cyanide is mentioned: [Pg.144]    [Pg.145]    [Pg.146]    [Pg.541]    [Pg.658]    [Pg.144]    [Pg.145]    [Pg.146]    [Pg.193]    [Pg.193]    [Pg.52]    [Pg.193]    [Pg.193]    [Pg.541]    [Pg.658]    [Pg.361]    [Pg.27]    [Pg.593]    [Pg.597]    [Pg.121]    [Pg.361]    [Pg.199]    [Pg.201]    [Pg.202]    [Pg.179]    [Pg.99]    [Pg.212]    [Pg.200]    [Pg.84]    [Pg.69]   
See also in sourсe #XX -- [ Pg.541 ]



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