Crystallization during storage

Can crystallize during storage, especially at temperatures below 60°F (15.6°C) dilutions are available to help lower crystallization temperatures... 

Can crystallize during storage crystallization temperature can be controlled by alkyl group functionality products are available with crystallization range between 60°F (15.5°C) and -40°F (-40.0°C)... 

The rearrangement products derived from aromatic and non-aromatic heterocyclic amines crystallize readily from the lower alcohols. Unlike those of many of the A-substituted glycosylamines, the crystals are not solvated. On the other hand, the ketose derivatives of aralkyl- and alkyl-amines, such as 2-phenylethylamine, ethanolamine, diethanolamine, glycine ethyl ester, and phenylalanine (see Table II), are hydrated or alcoholated, or both, and are difficult to isolate in pure crystalline form. The crystals which have been isolated were hygroscopic. Alcohols, aqueous alcohols, and water are the most commonly used solvents for crystallization. Acetone, ether, or benzene have been added to the alcoholic media in order to increase the yield of crystalline compound. The use of solvents that contain peroxides promotes decomposition of the crystals during storage. ... 

Stirring diorgano tellurium diethoxides in a diethyl ether/pentane medium with the stoichiometrically required amounts of 1,2-dihydroxyethane, 1,3-dihydroxypropane, 2-hydroxyphenylmethanol, 1,2-dihydroxybenzene, 2,2 -dihydroxybiphenyl, 2,3-dihydroxy-naphthalene, or 4-methylphenol produced diorgano tellurium alkoxides and phenoxides. These compounds precipitated as white solids from the reaction mixtures or separated as oils that crystallized during storage at low temperatures. The products of the transesterification with diols could be oligomeric. The low solubility of these compounds prevented the determination of their molecular masses . 

TABLE 13.3 Examples of Food Products For Which Crystallization During Storage Causes Product Dnects... 

Although it might at first seem surprising, this research on polar fish has attracted the attention of ice cream manufacturers. Premium quality ice cream is smooth it does not have large ice crystals in it. The makers of ice cream would like to incorporate these polar fish proteins, or molecules that behave similarly, into ice cream to prevent the growth of ice crystals during storage. 

C. Crystallization During Storage Formulation, Water Content, and the Glass Transition... 

Storage Will crystallize during storage below 50 F warm before use to eliminate crystals do not store above 70 F Ken-React KR 7 [Kenrich Petrochems.)... 

Gels usually remain in their phase state for some time and eventually collapse to amorphous precipitates. Tang et al. found that the hydrogel of the 1 2 mixture of 7 and 8 could spontaneously transfer into macroscopic crystals during storage. One related issue was to observe... 

Variable temperature/RH Raman or FTIR for heat/moisture-induced molecular demixing Spectral monitoring of crystallization during storage, etc., LF Raman susceptibility presents superior sensitivity to the phonon peaks from lattice vibration thus detect nanocrystaUites (30 A) even in low API content (2-5 %) MIR region highly susceptible to the interference from moisture peaks thus poses hurdle for hygroscopic samples... 

Some adhesive formulations may tend to crystallize during storage and would require storage above a certain temperature... 

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