Cross-coupling reactions alkyl electrophiles

Negishi E, Tan Z (2005) Diastereoselective, Enantioselective, and Regioselective Carbo-alumination Reactions Catalyzed by Zirconocene Derivatives. 8 139-176 Netherton M, Fu GC (2005)Pa]ladium-catalyzed Cross-Coupling Reactions of Unactivated Alkyl Electrophiles with Organometallic Compounds. 14 85-108 Nicolaou KC, King NP, He Y (1998) Ring-Closing Metathesis in the Synthesis of EpothUones and Polyether Natmal Products. 1 73-104 Nishiyama H (2004) Cyclopropanation with Ruthenium Catalysts. 11 81-92 Noels A, Demonceau A, Delaude L (2004) Ruthenium Promoted Catalysed Radical Processes toward Fine Chemistry. 11 155-171... 

Netherton M, Fu GC (2005) Palladium-catalyzed Cross-Coupling Reactions of Unactivated Alkyl Electrophiles with Organometallic Compounds. 14 85-108 Neumann H, see Jacobi von Wangelin A (2006) 18 207-221... 

Palladium- or nickel-catalyzed cross-coupling reactions Use of Alkyl Electrophiles Containing I, Br, Cl, and OTs... 

Sulfonium salts have been prepared on insoluble supports by S-alkylation of thioethers (Figure 8.2) only as synthetic intermediates. These compounds can be used to alkylate carboxylates [168] and halides [65], or as electrophiles for the Suzuki cross-coupling reaction (see Entry 7, Table 3.48 [169]). Sulfonium salts are also C,H-acidic, and can be used as intermediates for the synthesis of epoxides (Entry 7, Table 15.1 [170]). 

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