Cross-coupling organostannane with organic

Palladium-catalyzed cross-coupling reaction of organostannanes with organic halides, triflates, etc. For the catalytic cycle, see Kumada coupling on page 345. 

Allred, G. D., Liebeskind, L. S. Copper-Mediated Cross-Coupling of Organostannanes with Organic Iodides at or below Room Temperature. J. Am. Chem. Soc. 1996,118, 2748-2749. 

Kang, S. K., Kim, J. S., Choi, S. C. Copper- and manganese-catalyzed cross-coupling of organostannanes with organic iodides in the presence of sodium chloride. J. Org. Chem. 1997, 62, 4208-4209. 

The Pd-catalyzed carbonylative cross-coupling reaction of organic halides (or triflates) with organostannanes is an especially valuable and versatile synthetic method of un-symmetrical ketone. One serious drawback is the high toxicity of organostannanes. 

The Stille reaction involves the transition-metal-mediated cross-coupling of organostannanes with organic electrophiles. Generally, it is a mild and efficient way for the creation of C—C bonds, especially between Csp or Csp centers. The most significant disadvantage of the method is... 

The late Professor J. K. Stille pioneered the development of a very effective and versatile palladium-mediated C-C bond forming method - the palladium-catalyzed cross-coupling of organic electrophiles with organostannanes.48 This process continues to enjoy much success in organic synthesis because it proceeds in high yields under mild reaction conditions and because it tolerates a... 

The cross-coupling of organic electrophiles with organostannanes, commonly known as the Stille reaction, is one of the most versatile and selective palladium-catalyzed cross-coupling reactions [190]. Today, the Stille reaction is found among the routinely performed transformations in organic chemistry when it comes to... 

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