Anticommutation relations creation operators

We have seen that the creation operators anticommute among themselves (1.2.11) and that the same is true for the annihilation operators (1.2.12). We shall now establish the commutation relations between creation and annihilation operators. Combining (1.2.5) and (1.2.16), we obtain... 

Here frs and (ri-l tM> are, respectively, elements of one-electron Dirac-Fock and antisymmetrized two-electron Coulomb-Breit interaction matrices over Dirac four-component spinors. The effect of the projection operators is now taken over by the normal ordering, denoted by the curly braces in (15), which requires annihilation operators to be moved to the right of creation operators as if all anticommutation relations vanish. The Fermi level is set at the top of the highest occupied positive-energy state, and the negative-energy states are ignored. 

Following Ziesche [35, 55], in order to develop the theory of cumulants for noncommuting creation and annihilation operators (as opposed to classical variables), we introduce held operators /(x) and / (x) satisfying the anticommutation relations for a Grassmann held. 

The creation operators aj are the hermitian adjoint of the operators a . The properties of a can be inferred from the above equations. From Eq. (1.12) the hermitian conjugated operators are seen to satisfy the anticommutation relation... 

Using Eqs. (4.19) and (4.20a) it is easily verified that the anticommutation relations hold also for the transformed creation- and annihilation-operators. In Eq. (4.19) we have determined a unitary matrix that describes the... 

No signs of nonorthogonality showed up in these formulas. The anticommutation relation between a creation operator and an annihilation operator becomes... 

Show explicitly that the annihilation and creation operators fulfill the anticommutator relations (3 5). 

Second-quantization formalism was introduced into the theory of many-electron atoms by Judd [12]. This formalism enables one to give a simple and elegant description of both the rotation symmetry of a system and its permutational symmetry the tensorial properties of wave functions are translated to electron creation and annihilation operators, and the Pauli exclusion principle stems automatically from the anticommutation relations between these operators. 

Since these two equations hold for any one-determinant wave function, and the functions on the right side of these equations only differ in sign, we arrive at the following anticommutation relation for the creation operators ... 

The anticommutation relations between the electron creation and annihilation operators, accounting for (14.14), become... 

Using second-quantization, it is often necessary to transform complicated tensorial products of creation and annihilation operators. If, to this end, conventional anticommutation relations (14.19) are used, then one proceeds as follows write the irreducible tensorial products in explicit form in terms of the sum over the projection parameters of conventional products of creation and annihilation operators, then place these operators in the required order, and finally sum the resultant expression again over the projection parameters. On the other hand, the use of (14.21) enables the irreducible tensorial products of second-quantization operators to be transformed directly. 

Further we shall show that such linear combinations have a certain rank in the quasispin space of n lN2n2lN2 configuration. The commutation relations between tensors (17.8) or (17.9) are completely defined by the anticommutation relations for creation and annihilation operators. These relations can be written as... 

All four creation and annihilation operators for electrons in the pairing state (a,/ ) can be expressed via the tensor in (15.38) at various values of the projections v and m. The anticommutation relations (18.8) and... 

To proceed further, we have to know how to handle the products of creation and annihilation operators. It is Wick s theorem which tells us how to deal with the products of these operators. Before presenting Wick s theorem we have to introduce some necessary definitions and relations. The creation and annihilation operators satisfy the anticommutation relation... 

Due to the fact that the SLG wave function belongs to the GF approximation (Section 1.7), it is subject to numerous selection rules characteristic of GF. Their explicit form can be easily obtained using the second quantization formalism. Since the operators of electron creation on the right and left HOs satisfy usual anticommutation relations for orthogonal basis and the number of particle operators have the usual form ... 

The basic elements of the second-quantization formalism are the annihilation and creation operators (Linderberg and (3hrn, 1973). The annihilation operator ap annihilates an electron in orbital creation operator ap (the conjugate of ap) creates an electron in orbital p. These operators satisfy the anticommutation relations... 

Therefore, the anticommutation relation for a pair of creation operators is simply... 

Therefore, if we change the ordering of a pair of annihilation or creation operators, we must also change the sign of the resulting expression. Finally, it may be shown that the anticommutation relation for the mixed product is... 

The anticommutation relations of annihilation and creation operators given in Eqs. [19], [20], and [21] may be applied to the two terms on the right-hand side of this expression to give... 

By rearranging a given string of annihilation and creation operators into a normal-ordered form, matrix elements of such operators between determinan-tal wavefunctions may be evaluated in a relatively algorithmic manner. However, such an approach based on the direct application of the anticommutation relations can be quite tedious even for relatively short operator strings, and many opportunities for error may arise. 

The final combination, in which A is an annihilation operator and B is a creation operator, is not zero, however, owing to the anticommutation relations in Eq. [21]. Thus we write... 

Relative to direct application of the anticommutation relations for annihilation and creation operators, Wick s theorem helps to dramatically reduce the tedium involved in deriving the rather complicated amplitude equations above. However, as illustrated by Eq. [151], Wick s theorem still does not go far enough. Even if the cluster operator is truncated to include only double excitations, the resulting algebra provides many opportunities for error. Wlien even... 

Here and rjf are the usual annihilation and creation operators for electrons with y. and /S spin, respectively. In order to satisfy the Pauli exclusion principle, they must obey the anticommutation relations... 

From these definitions of electron creation and annihilation operators, the following anticommutator relations may be derived ... 

It follows from the above relations that the operator can be called the creation operator of the states nf, and bnf the annihilation operator for the same states. It also follows from (3.7) that the operators obey the anticommutation rules... 

These relationships can also be expressed in second-quantized form [4-8] by introducing Fermion creation and annihilation operators, which obey the anticommutation relations... 

Using the anticommutation relations (32), we can obtain the following commutation relations for the Kramers pair creation and annihilation operators [8] ... 

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