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Coulombic attraction, long-range

There are tliree important varieties of long-range forces electrostatic, induction and dispersion. Electrostatic forces are due to classical Coulombic interactions between the static charge distributions of the two molecules. They are strictly pairwise additive, highly anisotropic, and can be either repulsive or attractive. [Pg.185]

The inner layer (closest to the electrode), known as the inner Helmholtz plane (IHP), contains solvent molecules and specifically adsorbed ions (which are not hilly solvated). It is defined by the locus of points for the specifically adsorbed ions. The next layer, the outer Helmholtz plane (OHP), reflects the imaginary plane passing through the center of solvated ions at then closest approach to the surface. The solvated ions are nonspecifically adsorbed and are attracted to the surface by long-range coulombic forces. Both Helmholtz layers represent the compact layer. Such a compact layer of charges is strongly held by the electrode and can survive even when the electrode is pulled out of the solution. The Helmholtz model does not take into account the thermal motion of ions, which loosens them from the compact layer. [Pg.19]

The Coulombic electrostatic force is a very long-range force. When the distance is doubled, the force decreases to 50% when a molecule is removed to 10 times the normal distance, the attractive force declines to 10%. [Pg.86]

On the other hand, if we bring a proton up to the same nucleus, we will have a slightly different behavior. At first, the nucleus will repel the proton due to the long-range Coulomb force. Then, as we bring the proton very near to the surface, the same nuclear attraction will begin to overcome the repulsion. The nuclear attraction will increase until the proton is surrounded by nucleons as in the neutron case, but there will always be a net repulsion from the other protons. The repulsion decreases the overall attraction, and the proton potential energy well will not be... [Pg.139]


See other pages where Coulombic attraction, long-range is mentioned: [Pg.244]    [Pg.71]    [Pg.249]    [Pg.249]    [Pg.71]    [Pg.46]    [Pg.302]    [Pg.88]    [Pg.2521]    [Pg.350]    [Pg.353]    [Pg.60]    [Pg.277]    [Pg.53]    [Pg.168]    [Pg.167]    [Pg.336]    [Pg.245]    [Pg.254]    [Pg.18]    [Pg.663]    [Pg.670]    [Pg.671]    [Pg.34]    [Pg.167]    [Pg.456]    [Pg.404]    [Pg.157]    [Pg.201]    [Pg.185]    [Pg.580]    [Pg.150]    [Pg.322]    [Pg.241]    [Pg.53]    [Pg.131]    [Pg.13]    [Pg.727]    [Pg.376]    [Pg.136]    [Pg.230]    [Pg.239]    [Pg.60]    [Pg.167]    [Pg.217]    [Pg.201]   
See also in sourсe #XX -- [ Pg.24 ]




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Attractive range

Coulomb attraction

Long range

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