Cooling heat exchange function

Operating co.sts. Power requirements for air-cooled heat exchangers can be lower than at the summer design condition provided that an adequate means of air-flow control is used. The annual power requirement for an exchanger is a function of the means of airflow control, the exchanger seiwice, the air-temperature rise, and the approach temperature. 

Mixing of two saturated streams at different temperatures. This is commonly seen in the plume from a stack. Since vapor pressure is an exponential function of temperature, the resultant mixture of two saturated streams will be supersaturated at the mixed temperature. Uneven flow patterns and cooling in heat exchangers make this route to supersaturation difficult to prevent. 

All reactor modes sometimes can be operated advantageously with recycle of part of the product or intermediate streams. When the recycle is heated or cooled appropriately it can serve to moderate undesirable temperature travel. This function is well served with pumparound from a stirred tank through an external heat exchanger. Recycle streams also can be processed for changes in composition before return. 

The decrease in the heat duty of the pumparound heat exchanger would equal the increase in the heat duty of the overhead condenser. Thus, we say that the heat balance of the tower is preserved. Some of the heat that was being recovered to the cold fluid, shown in Fig. 12.2, is now lost to cooling water, in the overhead condenser. This shows the most important function of pumparounds recovering heat to a process stream that would otherwise be lost to the cooling tower. 

Duration of a cycle of HHP operation is defined as time required for reaction hydrogenation/dehydrogenation in pair hydride system. This time determines heat capacity of HHP. Duration of a cycle depends on kinetics of hydrogenation reactions, a heat transfer between the heated up and cooling environment, heat conductivities of hydride beds. Rates of reactions are proportional to a difference of dynamic pressure of hydrogen in sorbers of HHP and to constants of chemical reaction of hydrogenation. The relation of dynamic pressure is adjusted by characteristics of a heat emission in beds of metal hydride particles (the heat emission of a hydride bed depends on its effective specific heat conductivity) and connected to total factor of a heat transfer of system a sorber-heat exchanger. The modified constant of speed, as function of temperature in isobaric process [1], can characterize kinetics of sorption reactions. In HHP it is not sense to use hydrides with a low kinetics of reactions. The basic condition of an acceptability of hydride for HHP is a condition of forward rate of chemical reactions in relation to rate of a heat transmission. 

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