Sharp contact

Fig. 2 shows the CFRP-sandwich specimen and the transducer mounted on the scanner. Fig. 23 presents a C-scan of the specimen as first interesting result. Only the defects visible from the outside are indicated. The distance between transducer and specimen was smaller than the focal length, so that the angle of incidence at the edge of the sound beam converts the longitudinal waves to Rayleigh-waves in the specimen. These waves provide a very sharp image of the surface. This method opens the possibility for a non-contact acoustic microscope. 

In practice, it may be possible with care to float somewhat larger particles than those corresponding to the theoretical maximum. As illustrated in Fig. XIII-7, if the particle has an irregular shape, it will tend to float such that the three-phase contact occurs at an asperity since the particle would have to be depressed considerably for the line of contact to advance further. The resistance to rounding a sharp edge has been investigated by Mason and co-workers [62]. 

Film Theory. Many theories have been put forth to explain and correlate experimentally measured mass transfer coefficients. The classical model has been the film theory (13,26) that proposes to approximate the real situation at the interface by hypothetical "effective" gas and Hquid films. The fluid is assumed to be essentially stagnant within these effective films making a sharp change to totally turbulent flow where the film is in contact with the bulk of the fluid. As a result, mass is transferred through the effective films only by steady-state molecular diffusion and it is possible to compute the concentration profile through the films by integrating Fick s law ... 

Very high melt strength is also observed in situations where the molten polymer contacts a sharp object. Skin packaging trials have successfliUy packaged objects such as arrowheads and fishhooks in ionomer films. 

Powder coatings as a class are superior to Hquid coatings in abiHty to coat sharp edges and isolate the substrate from contact with corrosive environments. PVC coatings are softer and more flexible than any of the other powder coating materials. Primers used for PVC plastisols have been found generally suitable for powder coatings as weH (5). 

Fig. 13. Molion of a liquid interline across a sharp edge, (a) Close-up of movement over the sharp edge show.s that the liquid must exhibit the appropriate contact angle against the surface in front of it in order to advance over the edge, (b) Contact angle hysteresis resulting from the sharp edge.

Sharpe, L.H. and Schonhom, H. In Fowkes, F.M. (Ed.), Contact Angle, Wettability and Adhesion, Advances in Chemistry, Series 43. American Chemical Society, Washington, DC, 1964, p. 189. 

Once it is recognized that particles adhere to a substrate so strongly that cohesive fracture often results upon application of a detachment force and that the contact region is better describable as an interphase [ 18J rather than a sharp demarcation or interface, the concept of treating a particle as an entity that is totally distinct from the substrate vanishes. Rather, one begins to see the substrate-particle structure somewhat as a composite material. To paraphrase this concept, one could, in many instances, treat surface roughness (a.k.a. asperities) as particles appended to the surface of a substrate. These asperities control the adhesion between two macroscopic bodies. 

The line which defines the crystal surface can have straight pieces ( facets ) as well as curved ones. The latter correspond to a rough surface, as explained in the next section. The point at which straight and curved pieces meet can be either a sharp corner or a smooth tangential connection like z [21], where x is the deviation from the contact point in the direction... 

At any interface between two different phases there will be a redistribution of charge in each phase at the interface with a consequent loss of its electroneutrality, although the interface as a whole remains electrically neutral. (Bockris considers an interface to be sharp and definite to within an atomic layer, whereas an interphase is less sharply defined and may extend from at least two molecular diameters to tens of thousands of nanometres the interphase may be regarded as the region between the two phases in which the properties have not yet reached those of the bulk of either phase .) In the simplest case the interface between a metal and a solution could be visualised as a line of excess electrons at the surface of the metal and an equal number of positive charges in the solution that are in contact with the metal (Fig. 20.2). Thus although each phase has an excess charge the interface as a whole is electrically neutral. 

Knife-line Attack severe highly localised attack (resembling a sharp cut into the metal) extending only a few grains away from the fusion line of a weld in a stabilised austenitic stainless steel, which occurs when the metal comes into contact with hot nitric acid and is due to the precipitation of chromium carbides. 

The Alexander approach can also be applied to discover useful information in melts, such as the block copolymer microphases of Fig. 1D. In this situation the density of chains tethered to the interface is not arbitrary but is dictated by the equilibrium condition of the self-assembly process. In a melt, the chains must fill space at constant density within a single microphase and, in the case of block copolymers, minimize contacts between unlike monomers. A sharp interface results in this limit. The interaction energy per chain can then be related to the energy of this interface and written rather simply as Fin, = ykT(N/Lg), where ykT is the interfacial energy per unit area, q is the number density of chain segments and the term in parentheses is the reciprocal of the number of chains per unit area [49, 50]. The total energy per chain is then ... 

Microindentation hardness normally is measured by static penetration of the specimen with a standard indenter at a known force. After loading with a sharp indenter a residual surface impression is left on the flat test specimen. An adequate measure of the material hardness may be computed by dividing the peak contact load, P, by the projected area of impression1. The hardness, so defined, may be considered as an indicator of the irreversible deformation processes which characterize the material. The strain boundaries for plastic deformation, below the indenter are sensibly dependent, as we shall show below, on microstructural factors (crystal size and perfection, degree of crystallinity, etc). Indentation during a hardness test deforms only a small volumen element of the specimen (V 1011 nm3) (non destructive test). The rest acts as a constraint. Thus the contact stress between the indenter and the specimen is much greater than the compressive yield stress of the specimen (a factor of 3 higher). 

Fig. 1. Contact geometry for a sharp indenter at (A) zero load, (B) maximum load and (C) complete unload. The residual penetration depth after load removal is given by h...

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