Polymers conductive, crystalline inorganic

Composites of conducting polymer CP) and inorganic oxides are very attractive and perspective materials for different branches of science, namely for chemistry, physics, electronics, photonics etc. due to synergetic effect which arises under the integration of the properties of oxide and CP [7, 2]. In the present time the titaniiun IV) oxide (rutile and anatase crystalline modifications) is one among widely used inorganic oxides, which is applied for the chemical s5mthesis of such nanocomposites [3-7],... 

An example of fonnation of a conducting polymer shell around the inorganic kernel is shown in Figure 12.20. The amorphous polymer shell is in direct contact with the crystalline structure of the kernel. 

The charge excitations in the conducting polymers are quite different from those of usual inorganic semiconductors such as crystalline silicon, even though the... 

Crystalline Inorganic Hosts as Media for the Synthesis of Conductive Polymers... 

The higher thermal conductivity of inorganic fillers increases the thermal conductivity of filled polymers. Nevertheless, a sharp decrease in thermal conductivity around the melting temperature of crystalline polymers can still be seen with filled materials. The effect of filler on thermal conductivity for PE-LD is shown in Fig. 2.5 [22], This figure shows the effect of fiber orientation as well as the effect of quartz powder on the thermal conductivity of low density polyethylene. 

The ion conductivities of a range of TPEOCELL complexes with LiCFsSOs were examined by AC impedance spectroscopy from 293-373 K, so that all the complexes remained in the liquid-crystalline state during the measurements [235]. The inorganic salt concentration, indicated by the molar ratio of lithium ions to oxygens in the polymer chain, [Li]/[0], ranged from 0.038 to 0.125. The bulk conductivities were 10-6 Son-1 at ambient temperatures... 

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