Compositional evolution reservoirs

Oil and gas field waters have long been used in diagenetic studies, primarily as vehicles for understanding basin fluid flow, oil migration pathways, evolution of water composition, and reservoir com-partmentalization. However, water samples used for these purposes must be original formation water, not mixed with drilling mud or with injected fluids such as fracture fluid, waterflood water, or other fluids used for enhanced oil recovery (EOR),... 

The objective of this work is to study the possible influence of the crude oil composition on the amount of coke deposit and on its ability to undergo in-situ combustion. Thus, the results would provide valuable information not only for numerical simulation of in-situ combustion but also to define better its field of application. With this aim, five crude oils with different compositions were used in specific laboratory tests that were carried out to characterize the evolution of the crude oil composition. During tests carried out in a porous medium representative of a reservoir rock, air injection was stopped to interrupt the reactions. A preliminary investigation has been described previously (8). 

The evolution of the fluid composition reflects a lack of significant contact between the aqueous phase and the C02 while in the pore space of the reservoir. 

Grustal reservoirs are also variable in Gl-isotope compositions (Figs. 1-6) due to fractionation of the Gl-isotope compositions inherited from their mantle source through fluid-mineral reactions, incorporation of G1 derived from the oceans and fractionation within fluid reservoirs by diffusion (see below). For example, the oceanic crust is enriched in Gl (and pore fluids depleted in Gl) through reaction of seawater with basaltic crust derived from the depleted mantle (Fig. 1 Magenheim et al. 1995). Undoubtedly, future investigations of Gl-isotopes in whole rocks and mineral separates will address the Gl-isotope compositions of these reservoirs and their evolution. 

The common-lead method looks at the isotopic evolution of lead in systems with U/Pb and Th/Pb ratios similar to or less than the ratios in bulk solar system materials. The original formulation, by Holmes and Houtermans, is a single stage model that accounts for the isotopic composition of any sample of common lead in terms of primordial lead plus radiogenic lead produced in the source up to the time that lead was separated from uranium and thorium. Multistage models that more accurately describe the evolution of natural systems have been developed. The common-lead method is used in cosmochemistry primarily to study the time of differentiation and reservoir evolution in differentiated bodies... 

The atmosphere, ocean, and biosphere leave their record in sedimentary rocks. It is likely that this record reflects both secular and cyclic evolutionary processes. The cyclic processes involve chemical mass transfer of materials in and out of global reservoirs like the atmosphere, ocean, and sedimentary rocks. If inputs and outputs of these reservoirs are nearly balanced so that over long periods of geologic time the mass and composition of the reservoirs remain constant, a quasi-steady state is maintained. Hand-in-hand with this cyclicity go changes in Earth s surface environment reflecting secular evolution of the planet, an aging process. 

Stars form in dense cores within giant molecular clouds (see Fig. 1.4, Alves et al. 2001). About 1 % of their mass is in dust grains, produced in the final phases of stellar evolution. Molecular clouds are complex entities with extreme density variations, whose nature and scales are defined by turbulence. These transient environments provide dynamic reservoirs that thoroughly mix dust grains of diverse origins and composition before the violent star-formation process passes them on to young stars and planets. Remnants of this primitive dust from the Solar System formation exist as presolar grains in primitive chondritic meteorites and IDPs. 

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