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Compositional data, modeling summarizing

To summarize, we know firstly from simple model-testing studies spanning the last 20 years that for almost all systems tested, the terminal model can be fitted to (kp) or composition data for a copolymerization system, but not both simultaneously. Secondly, more recent experimental and theoretical studies have demonstrated that the assiunption of the implicit penultimate model— that the penultimate imit affects radical reactivity but not selectivity—cannot be justified. Therefore, on the basis of existing evidence, the explicit penultimate model should replace the terminal model as the basis of free-radical copolymerization propagation kinetics, and hence the failure of the terminal model kp) equation must be taken as a failure of the terminal model and hence of the terminal model composition equation. This means that the terminal model composition equation is not physically valid for the majority of systems to which it has been apphed. [Pg.1890]

There is little available data to analyze the predictive at ty of these modek to evaluate the through-the-plane conductivity of composites in which tte fibers are randomly oriented within a plane. In Delmonte s text there is limited data on the thermal conductivity of carbon fiber reinforced polyamide 66 composites, measured through the thickness of the plane of orientation of the fibers [26]. This data is summarized in Table 3. The fiber aspect ratios were taken from Fig. 8, based on the assumption that sufficient 3-D mixing occurred in the compounding and injection molding machines to reduce the fibers to an aspect ratio compatible with the maximum fraction associated with a random isotropic condition. The Hatta and Taya model does quite well in predicting the thermal conductivity across the plane of fiber orientation for these composites. [Pg.20]

Once we have estimated the composition crude feed, we must also collect data that summarize the column operating conditions and profile. Table 2.44 is a basic list of data that we require to develop a reasonable model for the atmospheric unit... [Pg.68]

His results are summarized in Table 13.6 in terms of the average absolute deviation in predicted vapor phase compositions and total pressures for the 73 systems. The poor results for model 1, which uses the infinite dilution activity coefficients, reflect the uncertainty in evaluating them, especially when low composition data are not available. The remaining... [Pg.488]

Table VI summarizes values of the activity coefficient ratio Ygr-/YC].- in the saturated solution for each average solid composition (as calculated from the model of Table II), the calculated provisional equilibrium distribution coefficient (Equation 12) and the provisional equilibrium aqueous solution activity ratio of Br to Cl- (Equation 13) based on the data of Table V. Table VI summarizes values of the activity coefficient ratio Ygr-/YC].- in the saturated solution for each average solid composition (as calculated from the model of Table II), the calculated provisional equilibrium distribution coefficient (Equation 12) and the provisional equilibrium aqueous solution activity ratio of Br to Cl- (Equation 13) based on the data of Table V.
Abstract Although once it was thought that main-sequence stars are remarkably homogeneous with respect to their chemical composition, the upper main-sequence stars (30000 > Te > 7000) show a variaety of chemically peculiar stars besides the so-called normal stars. Those include the Am, Ap, A Bootis, He-deficient, and He-rich stars. This review summarizes the current data, which are necessary to construct and test the theoretical models of these stars. In the second half of the review we concentrate on Li. In the lower main-sequecnce stars abundances of Li have been determined in hundreds of stars. Some of the remarkable results are ... [Pg.2]

Kempter50 studied the thermal decomposition of 88% dense NbC cylinders from 2273 to 3473 K in 1 atm of He. Data at 3273 K will be used to test our diffusion-coupled vaporization mass loss model. We transposed the cylindrical geometry into an equivalent slab by dividing the volume by the average vaporizing area. One face of the cylinder was not included in the calculation because it rested on a NbC pedestal in the furnace. Table 3.13. summarizes analytical X-ray data for average C/Nb compositions. [Pg.51]

Figure 3 summarizes the results of all the experiments. These data clearly demonstrate the failure of the classical lipid barrier model. Firstly, the upper set of data (A) show that the composition of the receiver solution significantly influences g-estradiol flux the simple model would predict that the P value ought to be constant in this case. Secondly, a simple lipid barrier model would have predicted that the lower two sets of data (B and C) should be superimposed, however the B and C results are significantly different. [Pg.234]

Similar well fitting simulation curves for the experimental stress-strain data as those shown in Fig. 46b can also be obtained for higher filler concentrations and silica instead of carbon black. In most cases, the log-normal distribution Eq. (55) gives a better prediction for the first stretching cycle of the virgin samples than the distribution function Eq. (37). Nevertheless, adaptations of stress-strain curves of the pre-strained samples are excellent for both types of cluster size distributions, similar to Fig. 45c and Fig. 46b. The obtained material parameters of four variously filled S-SBR composites used for testing the model are summarized in Table 4, whereby both cluster... [Pg.73]

Of all the estimates in Table 9, that of Taylor and McLennan (1985, 1995) stands out as being the most mahc overall (Figures 15 and 16). This mahc composition stems from their model for Archean crust, which constimtes 75% of their crust and is composed of a 2 1 mixture of mafic-to felsic-igneous rocks. This relatively mafic crust composition was necessitated by their inferred low heat production in Archean crust and the inferred large proportion of the Archean-aged crust. However, such a high proportion of mafic rocks in the Archean crust is at odds with seismic data (summarized in Section 3.01.3), which show that the crust of most Archean cratons is dominated by low velocities, implying the presence of felsic (not mafic) compositions, even in the lower crust. In addition, some of the... [Pg.1314]


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