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COMMERCIAL ORGANIC PEROXIDES

Decomposition Hazards. The main causes of unintended decompositions of organic peroxides are heat energy from heating sources and mechanical shock, eg, impact or friction. In addition, certain contaminants, ie, metal salts, amines, acids, and bases, initiate or accelerate organic peroxide decompositions at temperatures at which the peroxide is normally stable. These reactions also Hberate heat, thus further accelerating the decomposition. Commercial products often contain diluents that desensitize neat peroxides to these hazards. Commercial organic peroxide decompositions are low order deflagrations rather than detonations (279). [Pg.132]

Etee-tadical reactions ate accompHshed using a variety of processes with different temperature requirements, eg, vinyl monomer polymerization and polymer modifications such as curing, cross-linking, and vis-breaking. Thus, the polymer industries ate offered many different, commercial, organic peroxides representing a broad range of decomposition temperatures, as shown in Table 17 (19,22,31). [Pg.135]

See other commercial organic peroxides, diacyl peroxides, organic acids... [Pg.988]

MRH values calculated for 15 combinations with oxidisable materials are given. See Other ALKYL HYDROPEROXIDES, COMMERCIAL ORGANIC PEROXIDES... [Pg.1043]

See entry commercial organic peroxides See other 1-oxyperoxy compounds... [Pg.1175]

See other COMMERCIAL ORGANIC PEROXIDES, DIACYL PEROXIDES... [Pg.1198]

COMMERCIAL ORGANIC PEROXIDES, CRYSTALLINE HYDROGEN PEROXI-DATES... [Pg.306]

Prices of commercial organic peroxides range from ca 2.50 to > 35/kg. depending on peroxide type, production volume, assay, nature of formulation. cost of raw materials, and degree of special processing and handling requirements. [Pg.1239]

Recommendations for safe handling and storage of commercial organic peroxides are available from organic peroxide manufactures. [Pg.1240]

Excluding the peroxyacids, which are used primarily as epoxidizing and bleaching agents, approximately 90% of the commercial organic peroxides are consumed by the polymer mdustiy. [Pg.1240]

Slightly shock-sensitive, the commercial dry 95% material is highly hazard-rated. See other COMMERCIAL ORGANIC PEROXIDES, PEROXYESTERS... [Pg.1056]

See entry COMMERCIAL ORGANIC PEROXIDES See other 1-OXYPEROXY COMPOUNDS... [Pg.1223]

See other pages where COMMERCIAL ORGANIC PEROXIDES is mentioned: [Pg.221]    [Pg.222]    [Pg.223]    [Pg.131]    [Pg.131]    [Pg.132]    [Pg.133]    [Pg.133]    [Pg.133]    [Pg.133]    [Pg.134]    [Pg.997]    [Pg.91]    [Pg.92]    [Pg.107]    [Pg.300]    [Pg.301]    [Pg.72]    [Pg.73]    [Pg.88]    [Pg.281]    [Pg.282]    [Pg.841]    [Pg.1239]    [Pg.1239]    [Pg.1239]    [Pg.221]    [Pg.222]    [Pg.223]   
See also in sourсe #XX -- [ Pg.73 ]



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Organic peroxides

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