Clathrates kinetic stabilization

We have previously mentioned the kinetic stabilization toward racemization of methyl methanesulfinate included in the cage-type clathrate of TOT (59). Such an effect may indeed be expected, since the cage wall is fairly rigid and the heat... 

In the last 30 years or so. clathrate science has blossomed. with the reports of many new guests, a new hydrate structural family, a complete revision of the stmcture-size relationships, new approaches for hydrate characterization. refined models for hydrate stability prediction, high-level calculations and computational work on hydrate physical properties, experimental work and models for kinetic processes, etc. 

Inclusion Compounds Selectivity, Thermal Stability, and Kinetics, p. 696 Liquid. Clathrates, p. 804 Supramolecular Electrochemistry, p. 1412 Vibrational Spectroscopy, p. 1557 Weak Hydrogen Bonds, p. 1576... 

---