Chloroarene complexes, nucleophilic aromatic

Nucleophilic aromatic substitution reactions of haloarenes complexed to transition metal moieties with oxygen-, sulfin-, and nitrogen-containing nucleophiles allows for the synthesis of a wide variety of aryl ethers, thioethers, and amines. These metal-mediated reactions proceed under very mild conditions and allow for the incorporation of a number of different functional groups. Nucleophilic substitution reactions of chloroarenes complexed to the cyclopentadienyliron moiety have been the focus of many studies directed toward the design of functionalized organic monomers. ... 

C. Nucleophilic Aromatic Substitution Potymerization of Chloroarene Complexes... 

Keywords C-Cl activation, Ar-Cl oxidative addition, Chloroarenes, Homogeneous catalysis with metal complexes, Reductive dechlorination, Aromatic nucleophilic substitution, Heck reaction, Homocoupling, Cross-coupling, Carbonylation... 

---