Chloro trifluoromethane

SC, Thiocarbonyls, osmium, 26 185-187 SC4Hb, Thiophene, tetrahydro-gold complexes, 26 85-87 SCjHj, 2,4-Pentadienthial osmium complex, 26 188 SC H6, Benzenethiol osmium complex, 26 304 SClF,0,PtCiiHio, Platinum(II), chloro-bis-(triethylphosphine)(trifluoromethane-sulfonato)-cis-, 26 126... 

The formation of dimeric fluorinated products via heat-induced bond breaking has been more or less restricted to industrial processes. Thus, the pyrolysis of trifluoromethane (1) and chloro-difluoromethane (3) are the two industrial sources for tetrafluoroethene (2), hexafluoropropenc... 

SYNS (p-CHLOROPHENYL)TRIFLUOROMETHANE p-CHLOROTRIFLUOROMETHYLBENZENE 4-CHLOROTRIFLUOROMETHYLBENZENE 1-CHLORO-4-(TRIMETHYL)-BENZENE (9CI) a,a,a-TRIFLUORO-4-CHLOROTOLUENE p-(TRIFLUOROMETHYL)-CHLOROBENZENE p-TRIFLUOROMETHYLPHENYL CHLORIDE... 

CHLORO-l,l,2-TRIFLUOROETHYLENE see CLQ750 CHLOROTRIFLUOROMETHANE see CLR250 CHLOROTRIFLUOROMETHANE mixed with TRIFLUOROMETHANE see F00562 CHLOROTRIFLUOROMETHANE and TRIFLUOROMETHANE AZEOTROPIC MIXTURE pOT) see F00562... 

The formation of dimeric fluorinated products via heat-induced bond breaking has been more or less restricted to industrial processes. Thus, the pyrolysis of trifluoromethane (1) and chloro-difluoromethane (3) are the two industrial sources for tetrafluoroethene (2), hexafluoropropenc (4). and their corresponding oligomers and polymers.1-2 Hexafluoropropene (4) is formed as a byproduct in the pyrolysis of chlorodifluoromethane (3) however, a temperature-controlled pyrolysis of 3 has been worked out as a commercial process for the production of 4.3... 

CYCLOBOTANONES 1-Chloro-N.N,2-tiimethylpropenylamine. Hydrogen bromide. Lithium iodide. Trifluoromethane-sulfonic anhydride. 

C4HCIN2 cis-2-chloro-2-butenedinitrile 71200-79-8 445.15 38.640 1,2 2528 C4H4CIF303S 2-chloro-2-propenyl trifluoromethane sulfona 62861-56-7 310.90 26.059 1,2... 

Variations of the Ramberg-Backlund reaction have been described in which the usual halide ion is replaced by p-toluenesulfonate or p-toluene-, alkane- or trifluoromethane-sulfinate leaving groups. For example, Meyers has described a single transformation of the Ramberg-Backlund type of an a-tosyloxy sulfone (Scheme 9). The reaction is surprisingly slow, nearly 1000 times slower than that of the corresponding a-chloro sulfone under the same conditions, and this, of course, limits its value in synthesis. Another problem is the fact that the precursors are not easy to prepare. 

FjOgSj, Peroxydisulfuryl difluoride, 29 10 FjXe, Zenon difluoride, 29.1 F3Au2C103P4PtSC4,Hj , Platinum( 1+), chloro- 1-kC/ bis(triethylphosphine-lKP)bis(triphenylphosphineF2icP,3KP-triangulo-digold-, trifluoromethane-sulfonate, 27 218... 

Synonyms Benzene, 1-chloro-4(trifluoromethyO 4-Chlorobenzotrifluoride (p-Chlorophenyl)trifluoromethane 1 -Chloro-4-trifluoromethylbenzene 4-Chlorotrifluoromethylbenzene p-Chlorotrifluoromethylbenzene 4-Chloro-a,a,a-trifluorotoluene p-Chloro-a,a,a-trifluorotoluene 1-Chloro-4-jrimethyl)benzene Parachlorobenzotrifluoride PCBTF Toluene, p-chloro-a,a,a,-trifluoro a,a,a-Trifluoro-4-chlorotoluene p-(Trifluoromethyl)chlorobenzene p-Ttifluoromethylphenyl chloride Classificatirm Aromatic halogenated hydrocarbon Empirical C7H,CIF5... 

See Epoxy, bisphenol /Vepichlorohydrin 4-Chloro-3-methylphenol. See p-Chloro-m-cresol Chlorooxobismuthine. See Bismuth oxychloride Chloroparaffin. See Paraffin, chlorinated p-Chlorophenyl chloride. See p-Dichlorobenzene a-[2-(4-Chlorophenyl)ethyl]-a-(1,1 -dimethylethyl)-1 H-1,2,4-triazole-1 -ethanol. SeeTebuconazole Chlorophenylmethane. See Benzyl chloride (p-Chlorophenyl)trifluoromethane. See p-Chlorobenzotrlfluorlde... 

Preparation by reaction of p-chloro-benzoic acid with 4-hydroxytnpiienyl in the presence of trifluoromethane-sulfonic acid, first at 50° for 23 h, then at 70° for 4 h (97%) [151]. 

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