Chlorine dioxide oxidations

R. G. Rice and J. A. Cotmvo, eds., O nej Chlorine Dioxide Oxidation Products of Organic Materials, International Ozone Association, Cleveland, Ohio, 1978. 

Chlorine. Chlorine is a weU known disinfectant for water and wastewater treatment, however, it can react with organics to form toxic chlorinated compounds such as the tribalomethanes bromodichloromethane, dibromochloromethane, chloroform [67-66-3] and bromoform [75-25-2]. Chlorine dioxide [10049-04-4] may be used instead since it does not produce the troublesome chlorinated by-products as does chlorine. In addition, by-products formed by chlorine dioxide oxidation tend to be more readHy biodegradable than those of chlorine, however, chlorine dioxide is not suitable for waste streams containing cyanide. 

Taymaz, K., Williams, D.T., and Benoit, F.M. Chlorine dioxide oxidation ofaromatic hydrocarbons commonly found in water. 

Rosenblatt DH, Hull LA, DeLuca DC, Davis GT, Weglein RC and Williams HKR, Oxidations of amines. II. Substituent effects in chlorine dioxide oxidations, JACS, 89 1158-1163 (1967). Cited in Perrin Bases suppl. no. 4961, ref. R22a. Used a glass electrode in a cell wiBi liquid junction potentials. Solutions were carbonate-free. No activity corrections were made. Calibrated pH meter at pH = 7.00 and 10.00. 

Helz, G. R., R. Y. Hsu, and R. M. Block. 1978. Bromoform production by oxidative biocides in marine waters. In R. G. Rice and J. A. Cotruvo, Eds. Ozone-Chlorine Dioxide Oxidation Products of Organic Materials. (Cleveland, OH Ozone Press Inti.), pp. 68-76. 

Lindgren, B. O., C. M. Svahn, and G. Widmark. 1965. Chlorine dioxide oxidation of cyclohexene. Acta Chem. Scand. 19 7-13. 

Studies of chlorine dioxide oxidation of a series of meta- and para-substituted benzyldimethylamines (187) gave good Hammett plots, with log = 4.45... 

Chlorine dioxide oxidizes triethylamine to the secondary amine and acetaldehyde (equation 63) a free-radical mechanism was proposed... 

Chlorine dioxide oxidizes iodide ion in aqueous solution to iodine chlorine dioxide is reduced to chlorite ion. 

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