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Chemical structure, hydrolytic degradation rate

ViUuendas I., Molina I., Regano C., Bueno M., Martinez de Ilarduya A., Galbis J.A., Munoz-Guerra S., Hydrolytic degradation of poly(ester amidejs made from tartaric and succinic acids. Influence of the chemical structure and microstructure on degradation rate. Macromolecules, 32, 1999, 8033-8040. [Pg.112]

In parallel, the physical structure of PLA has been reported to affect its hydrolytic degradation mechanism. For example, it has been found that the hydrolytic chain cleavage proceeds preferentially in the amorphous regions, leading to the increase in polymer crystallinity. The rate of the degradation reaction seems also to be affected by the shape of the specimen and by the chemical structure of the polymer, as well as by the conditions under which the hydrolysis is performed, including pH and temperature. ... [Pg.290]


See other pages where Chemical structure, hydrolytic degradation rate is mentioned: [Pg.290]    [Pg.645]    [Pg.137]    [Pg.604]    [Pg.980]    [Pg.155]    [Pg.12]    [Pg.304]    [Pg.143]    [Pg.309]    [Pg.319]    [Pg.155]    [Pg.441]    [Pg.160]    [Pg.179]    [Pg.253]    [Pg.86]    [Pg.103]    [Pg.325]    [Pg.335]    [Pg.355]    [Pg.518]    [Pg.981]    [Pg.570]    [Pg.19]    [Pg.143]    [Pg.25]    [Pg.123]   
See also in sourсe #XX -- [ Pg.296 ]




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Chemical degradation

Chemical rate

Degradation chemical structure

Degradation rates

Hydrolytic

Hydrolytic degradation

Hydrolytic rate

Hydrolytic structure

Structural degradation

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