Classifying Chemical Reactions

For one day, record situations that suggest that a chemical change has occurred. Identify the reactants and the products, and state whether there is proof of a chemical reaction. Classify each of the chemical reactions according to the five common reaction types discussed in the chapter. 

Table 0.1 Chemical Reactions Classified According to the Contacting Phases and an Example from Industry...

Surface chemical reactions can be classified into tliree major categories [29] ... 

Chemists usually learn about reactions according to fiinctional groups for example, How can I make an aldehyde and what reactions are known for aldehydes " This is clearly not a very good starting point for classifying reactions. The poor state of affairs in the definition of reaction types is further quite vividly illustrated by the fact that many chemical reactions are identified by being named after their inventor Diels-Alder reaction, Michael addition, Lobry-de Bruyn-van Ekenstein rear-... 

A more detailed classification of chemical reactions will give specifications on the mechanism of a reaction electrophilic aromatic substitution, nucleophilic aliphatic substitution, etc. Details on this mechanism can be included to various degrees thus, nucleophilic aliphatic substitutions can further be classified into Sf l and reactions. However, as reaction conditions such as a change in solvent can shift a mechanism from one type to another, such details are of interest in the discussion of reaction mechanism but less so in reaction classification. 

In the last section we examined some of the categories into which polymers can be classified. Various aspects of molecular structure were used as the basis for classification in that section. Next we shall consider the chemical reactions that produce the molecules as a basis for classification. The objective of this discussion is simply to provide some orientation and to introduce some typical polymers. For this purpose a number of polymers may be classified as either addition or condensation polymers. Each of these classes of polymers are discussed in detail in Part II of this book, specifically Chaps. 5 and 6 for condensation and addition, respectively. Even though these categories are based on the reactions which produce the polymers, it should not be inferred that only two types of polymerization reactions exist. We have to start somewhere, and these two important categories are the usual place to begin. 

X-Amino acids ate ampholytic compounds. The chemical reactions of amino acids can be classified according to their carboxyl, amino, and side-chain groups. Most of the reactions have been well known for a long time the details of these reactions have been reviewed (77). 

The drying mechanisms of desiccants may be classified as foUows Class 1 chemical reaction, which forms either a new compound or a hydrate Class 2 physical absorption with constant relative humidity or vapor pressure (solid + water + saturated solution) Class 3 physical absorption with variable relative humidity or vapor pressure (soHd or liquid + water + diluted solution) and Class 4 physical adsorption. 

Mixer-Settler Equipment The equipment for extraction or chemical reaction may be classified as follows ... 

Atmospheric chemical reactions are classified as either photochemical or thermal. Photochemical reactions are the interactions of photons with species which result in the formation of products. These products may undergo further chemical reaction. These subsequent chemical reactions are called thermal or dark reactions. 

The chemical reactions of XY can be conveniently classified as (a) halogenation reactions, (b) donor-acceptor interactions and (c) use as solvent systems. Reactions frequently parallel those of the parent halogens but with subtle and revealing differences. CIF is an effective fluorinating agent (p. 820) and will react with many metals and non-metals either at room temperature or above, converting them to fluorides and liberating chlorine, e.g. ... 

Once such effects had been noted, it became necessary to interpret the observed results and to classify the solvents. The earliest attempts at this were by Stobbe, who reviewed the effects of solvents on keto-enol tautomers [4]. Since then many attempts have been used to explain solvent effects, some based on observations of chemical reactions, others on physical properties of the solvents, and yet others on spectroscopic probes. All of these have their advantages and disadvantages and no one approach can be thought of as exclusively right . This review is organized by type of measurement, and the available information is then summarized at the end. 

The majority of potentiometric titrations involve chemical reactions which can be classified as (a) neutralisation reactions, (b) oxidation-reduction reactions, (c) precipitation reactions or (d) complexation reactions, and for each of these different types of reaction, certain general principles can be enunciated. 

In this study, the flame can be classified as a wrinkled flame throughout most of the flow field. The main findings of [25] are related to both (1) the question of how the turbulent velocity field is affected by the chemical reaction and induced expansion phenomena and (2) the measurements of mean flame surface density and the... 

The overall stability of the complexes listed in Table II tends to parallel, but exceed, that of their alkyl counterparts. Their chemical reactions may be classified as shown in the headings to Sections II,C,l-5, respectively, of which the Si—M cleavages (Section II,C,3) have been the most studied. 

Many chemical reactions can be classified by either abstraction or addition-elimination mechanisms. Abstraction mechanisms are common in the reaction of radicals with closed-shell species, such as the reaction... 

It is obviously impossible to classify chemical reactions in a completely logical manner, and the editors have in general based their classification on types of chemical element, compound or reaction rather than on mechanisms, since views on the latter are subject to change. Some duplication is inevitable, but it is felt that this can be a help rather than a hindrance. 

The chemical reaction represented by the equation would be classified as a —... 

Classify reactions as single-replacement chemical reactions. 

Chemical reactions accompanying the electrode reaction can be classified from three points of view. They can be sufficiently fast so that they proceed... 

Almost all the specific chemical reactions in biodegradation can be classified as oxidation-reduction, hydrolysis, or conjugation. Hydrolysis and oxidation-reduction have been discussed before. Conjugation involves the addition of functional groups or a hydrocarbon moiety to an organic... 

After understanding the generation of various free radicals as a result of ultrasonic propagation and cavitation in pure water as well as in the presence of different gases, we can perhaps understand the aqueous chemical reactions better. However, for the sake of simplicity, all reactions involving inorganic species, have been broadly classified into following sections and would be taken up one by one... 

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