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Chelate five-membered

In contrast to the other aldoses, the copper atoms find an especially favorable coordination environment for lyxose and mannose. Cu(II), indeed, has the ability to build stable complexes with the pyranoid trans-daoX fragments, shown for the complexed 3,4-diol functions, but the more flat chelate five-membered rings, which are built with the with pyranoid m-diol fragments, seemed to be more favorable for copper centers. [Pg.1132]

The carbopalladation of allylamine with malonate affords the chelating complex 510, which undergoes insertion of methyl vinyl ketone to form the amino enone 511[463]. The allylic sulfide 512 has the same chelating effect to give the five-membered complex 513 by carbopalladation[463.464]. [Pg.95]

Particularly alkyl halides which have a perfluoroalkyl group at the /3-position undergo smooth carbonylation. Probably the coordination of fluorine to form a five-membered chelate ring accelerates the reaction. Double carbonylation to give the a-keto amide 915 is possible in Et NH with the fluorine-bearing alkyl iodide 914[769,770]. The ester 917 is obtained by the carbonylation of the /3-perfluoroalkyl iodide 916 in ethanol. [Pg.262]

EthylenediaminetetraaceticAcid. Ethylenediaminetetraacetic acid (EDTAH has six potential donor groups two nitrogen atoms and four carboxylate groups. If EDTA 4— acts as a hexadentate ligand to a metal, the resulting complex contains five five-membered chelate rings and has a charge that is four less than that of the metal ion. [Pg.438]

Ketone 13 possesses the requisite structural features for an a-chelation-controlled carbonyl addition reaction.9-11 Treatment of 13 with 3-methyl-3-butenylmagnesium bromide leads, through the intermediacy of a five-membered chelate, to the formation of intermediate 12 together with a small amount of the C-12 epimer. The degree of stereoselectivity (ca. 50 1 in favor of the desired compound 12) exhibited in this substrate-stereocontrolled addition reaction is exceptional. It is instructive to note that sequential treatment of lactone 14 with 3-methyl-3-butenylmagnesium bromide and tert-butyldimethylsilyl chloride, followed by exposure of the resultant ketone to methylmagnesium bromide, produces the C-12 epimer of intermediate 12 with the same 50 1 stereoselectivity. [Pg.239]

When, however, the ligand molecule or ion has two atoms, each of which has a lone pair of electrons, then the molecule has two donor atoms and it may be possible to form two coordinate bonds with the same metal ion such a ligand is said to be bidentate and may be exemplified by consideration of the tris(ethylenediamine)cobalt(III) complex, [Co(en)3]3+. In this six-coordinate octahedral complex of cobalt(III), each of the bidentate ethylenediamine molecules is bound to the metal ion through the lone pair electrons of the two nitrogen atoms. This results in the formation of three five-membered rings, each including the metal ion the process of ring formation is called chelation. [Pg.52]

However, EDTA has the widest general application in analysis because of its powerful complexing action and commercial availability. The spatial structure of its anion, which has six donor atoms, enables it to satisfy the coordination number of six frequently encountered among the metal ions and to form strainless five-membered rings on chelation. The resulting complexes have similar structures but differ from one another in the charge they carry. [Pg.57]

The X-ray crystallographic analysis of the unsymmetrical BisP shows a strong distortion of the five-membered chelation ring as compared to that of symmetric BisP [32]. The large difference in the steric repulsions between the bulky substituent borne on one phosphorus atom and the neighboring atoms on the one hand and the other (different) bulky substituent borne on the other phosphorus atom and the same neighboring atoms on the other hand is believed to be responsible for better steric matching with some substrates. [Pg.31]

The chelate ring size principle can have structural effects as well as effects on thermodynamic stability in aqueous solution. An example is coordination of metal ions by sugars (44). The cyclic polyol cts-inositol can coordinate metal ions in two distinct ways (Fig. 14) (45). In ax-ax-ax bonding (Fig. 14), the metal ion is part of three fused six-membered chelate rings. Alternatively, in ax-eq-ax coordination, the metal ion is part of two fused five-membered and one six-membered chelate rings. Angyal has noted that metal ions of radius more than 0.8 A adopt the ax-eq-ax structure (44), whereas with an ionic radius... [Pg.117]

In the four-coordinate complexes (12) (X = Cl, Br) the phenol phosphine is coordinated as a monodentate.151 In the presence of base, the phenolate O atom deprotonates and coordinates to give (13). The five-membered chelate ring in this complex is resistant to protonation, and ringopening is not observed even in the presence of CO or C2H4. [Pg.14]


See other pages where Chelate five-membered is mentioned: [Pg.287]    [Pg.194]    [Pg.435]    [Pg.999]    [Pg.999]    [Pg.307]    [Pg.70]    [Pg.70]    [Pg.999]    [Pg.176]    [Pg.287]    [Pg.194]    [Pg.435]    [Pg.999]    [Pg.999]    [Pg.307]    [Pg.70]    [Pg.70]    [Pg.999]    [Pg.176]    [Pg.87]    [Pg.108]    [Pg.438]    [Pg.205]    [Pg.386]    [Pg.169]    [Pg.411]    [Pg.230]    [Pg.234]    [Pg.243]    [Pg.326]    [Pg.503]    [Pg.2]    [Pg.707]    [Pg.710]    [Pg.714]    [Pg.113]    [Pg.127]    [Pg.243]    [Pg.97]    [Pg.261]    [Pg.26]    [Pg.48]    [Pg.275]    [Pg.112]    [Pg.115]    [Pg.117]    [Pg.119]    [Pg.119]    [Pg.121]    [Pg.125]   
See also in sourсe #XX -- [ Pg.17 ]




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Chelate ring five-membered

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Chelation structure five-membered

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