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Charge Madelung energy

A metallic band structure is realized when the CT solids have a partial CT state and molecules form uniform segregated columns or layers. Figure 1 shows electrical conductivity data for 1 1 low-dimensional TTF TCNQ system, as a function of redox potentials [82]. The two lines a and b are related to the equation expressing the relationship between 7d, Ea, and the Madelung energy M 5) (5 = degree of CT) between partially charged component molecules (eq. 2) [83], where and Ea are... [Pg.73]

Reduced Madelung energies are converted into familiar units by specifying actual charges (integer Z), such that... [Pg.188]

Neutral DA charge transfer complexes D . A ( 0) have a lower melting point than those of ionic DA complexes (8 > 0.5), since the Madelung energy in the neutral DA makes a much smaller contribution to the lattice energy. For the... [Pg.278]

The energy terms relevant for this crystal structure are the electrostatic Madelung energy obtained for the ionic crystal and the energy of charge... [Pg.64]

See other pages where Charge Madelung energy is mentioned: [Pg.234]    [Pg.234]    [Pg.71]    [Pg.32]    [Pg.32]    [Pg.45]    [Pg.61]    [Pg.23]    [Pg.4]    [Pg.146]    [Pg.361]    [Pg.149]    [Pg.238]    [Pg.351]    [Pg.351]    [Pg.357]    [Pg.436]    [Pg.437]    [Pg.648]    [Pg.648]    [Pg.716]    [Pg.4]    [Pg.192]    [Pg.308]    [Pg.309]    [Pg.7]    [Pg.161]    [Pg.163]    [Pg.482]    [Pg.492]    [Pg.493]    [Pg.795]    [Pg.413]    [Pg.12]    [Pg.13]    [Pg.9]    [Pg.111]    [Pg.97]    [Pg.29]    [Pg.13]    [Pg.280]    [Pg.306]    [Pg.450]    [Pg.65]    [Pg.128]   
See also in sourсe #XX -- [ Pg.783 ]



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Energy charge

Madelung energy

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