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Smaller PNC contributions

The first correction we consider is the effect of the Breit interaction. It is taken into account by replacing the Coulomb interaction V in the basic Hamiltonian of Eq. (55) by the sura of the Coulomb and Breit interactions. [Pg.510]

With this replacement, the HF equations for the single-particle orbitals become [Pg.510]

Since the dominant contribution to the PNC amplitude is the PNC-HF contribution, it is sufficient to carry out a PNC-HF calculation including [Pg.510]


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