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Characteristic temperature ionic solutions

Transport of the gaseous species from the donor to the acceptor stream depends on several parameters, e.g., temperature, ionic strength, surface tension, contact time between the solutions and the semi-permeable medium, the characteristics of this medium (active surface, porosity, thickness), the partition coefficient between the fluid and the membrane,... [Pg.367]

Theoretical studies and the application of chemical reactions within the matrix of various molecular and ionic solvents are among the most important trends in modern chemistry and engineering since the nature of the solvent significantly affects the technological processes running in it [1, 2], Modern solution technologies are mainly based on the use of molecular liquids as solvents at room temperature. However, an increase in the application of high-temperature ionic melts as liquid media has been evident in recent decades. This is a consequence of a number of unique features which are characteristic of this class of solvents. [Pg.393]

If a solid and compact continuous film of corrosion products is formed on the metal surface, having the characteristics of ionic conduction, the anodic process can take place at the interface between the corrosion products and the solution. However, at low temperatures, the low ionic mobility in solids and the low charge carrier concentration limit the ionic transport through the corrosion products, and the rate of the anodic process may be reduced to negligible values from a corrosion point of view, such as in the case of materials in a passivity condition. If the corrosion products are not conductors, the anodic process can be limited to the free metal surface through the porosity of the corrosion product. [Pg.318]

There are a variety of properties that can affect the transport of proteins through hydrophilic materials. These include the effects of pH, temperature, ionic strength, and solvent. The characteristics ofthe solute (size, shape, and ionizability) and the polymer are also important in determining the transport behavior. [Pg.151]

The factors that affect the activity coefficient are the temperature r, the ionic strength w, the dielectric constant e, the ion charge Zf, the size of the ion in angstroms and the density of the solvent d. All of these factors are characteristics of the solution which relate the activity to the concentration by two main effects. The first is the salt effect designated as/ H+ It can be approximated for the hydrogen ion by the expression... [Pg.4]

Proton Transfers in More Concentrated Solutions. In discussing ions in solution, one of our major interests has been the ionic environment and the problem of disentangling characteristic and intrinsic ionic properties from the effects that result from a change of environment. We have discussed the change of temperature, and more than once we have examined the effect of changing from one solvent to another. In this chapter we shall consider a change of environment of another kind. [Pg.240]

Near room temperature most gases become less soluble in water as the temperature is raised. The lower solubility of gases in warm water is responsible for the tiny bubbles that appear when cool water from the faucet is left to stand in a warm room. The bubbles consist of air that dissolved when the water was cooler it comes out of solution as the temperature rises. In contrast, most ionic and molecular solids are more soluble in warm water than in cold (Fig. 8.22). We make use of this characteristic in the laboratory to dissolve a substance and to grow crystals by letting a saturated solution cool slowly. However, a few solids containing ions that are extensively hydrated in water, such as lithium carbonate, are less soluble at high temperatures than at low. A small number of compounds show a mixed behavior. For example, the solubility of sodium sulfate decahydrate increases up to 32°C but then decreases as the temperature is raised further. [Pg.444]

In this work, an experimental study was conducted on gelatin in semi-dilute region in water solution and research the effect of temperature, pH, zeta potential, and ionic strength on hydrodynamic properties by viscometiy, in order to determine the conformational characteristic, and phase transition (Tgei). [Pg.88]


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