Catalytic cross-coupling

Catalytic cross-coupling reactions in synthesis of bihetarenes and arylhetarenes 98T263. 

Nucleophilic phosphinations, Grignard-reactions and catalytic cross-coupling for preparation of sulfonated phosphines... 

S. P. Stanforth, Catalytic Cross-Coupling Reactions in Biaryl Synthesis, Tetrahedron 1998, 54, 263-303. 

Hillier AC, Grasa GA, Viciu MS, Lee HM, Yang CL, Nolan SP (2002) Catalytic cross-coupling reactions mediated by palladium/nucleophilic carbene systems. J Qrganomet Chem 653 69-82... 

Catalytic Cross Coupling with Organostannanes and Organosilanes, the Stille and Hiyama Reactions... 

Catalytic Cross Couplings with Organoboranes, the Suzuki or Suzuki-Miyaura Reaction... 

Catalytic Cross Couplings to Terminal Alkynes, the Sonogashira Reaction... 

Catalytic Cross Couplings of Aryl Halides with Enolates... 

Catalytic Cross Couplings of Aryl Halides to Nitrogen and Oxygen Nucleophiles, the Buchwald-Hartwig Reaction... 

Stanforth S. P. Catalytic Cross-coupling reactions in biaryl synthesis. Tetrahedron 1998 54 263-303. 

The formation of unsymmetric biaryls via catalytic cross-coupling of aryl halides and organometallic compounds has been shown to proceed in ionic liquids with enhanced activity. The Suzuki-Miyaura cross coupling (cf. Section 2.11)... 

This organolanthanide-catalyzed reaction provides the first example of efficient preparation of well-defined propiolamidines, a new family of amidines which are difficult to access by other means and may show unique reactivity. A wide range of terminal alkynes could be used for this catalytic cross-coupling reaction which was not affected by either electron-withdrawing or -donating substituents or their positions at the phenyl ring of the aromatic alkyne [68]. 

The concept of atom economy has frequently been used to emphasize the minimal number of reactants, as well as selection of low energy starting materials as substrates [7], for example, using substrates that contain a reactive C-H bond rather than a C-X bond. Ideally, a direct catalytic cross-coupling reaction that utilizes traditionally inert C-H bonds would underline this concept as only the loss of nontoxic hydrogen gas or water as by-products would be necessitated (Scheme 3). 

Stuart DR, Fagnou K (2007) The catalytic cross-coupling of unactivated arenes. Science 316 1172-1175... 

Cross coupling , Acc. Chem. Res. 2008, 41, Special issue (11), 1439-1564 Metal-Catalyzed Cross-Coupling Reactions , 2nd Edn, de Meijere, A. and Diederich, F, Eds., Wiley-VCH, Weinheim, 2004 Catalytic cross-coupling reactions in biaryl synthesis , Stanforth, S. R, Tetrahedron, 1998, 54, 263 Organometallics in coupling reactions in 7t-deficient azaheterocycles , Undheim, K. and Benneche, T.,Adv. Heterocycl Chem., 1995, 62, 305. 

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