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Catalysts, for acetonation

Aldol condensation of acetone is a well-known base-catalyzed reaction, and barium hydroxide is one of the catalysts for this reaction mentioned in textbooks. A family of barium hydroxide samples hydrated to various degress determined by the calcination temperature (473, 573, 873, and 973 K) of the starting commercial Ba(OH)2 8H2O were reported to be active as basic catalysts for acetone aldol condensation (282,286). The reaction was carried out in a batch reactor equipped with a Soxhlet extractor, where the catalyst was placed. The results show that Ba(OH)2 8H2O is less active than any of the other activated Ba(HO)2 samples, and the Ba(OH)2 calcined at 473 K was the most active and selective catalyst for formation of diacetone alcohol, achieving nearly 58% acetone conversion after 8h at 367 K in a batch reactor. When the reaction temperature was increased to 385 K, 78% acetone conversion with 92% selectivity to diacetone alcohol was obtained after 8h. The yield of diacetone alcohol was similar to that described in the literature in applications with commercial barium hydroxide, but this catalyst required longer reaction times (72-120 h) (287). No deactivation of the catalyst was observed in the process, and it could be used at least 9 times without loss of activity. [Pg.289]

Catalysis, enzyme-substrate and intermediate compound theory in homo-and heterogeneous, V, 51 Catalysts, for acetonation, III, 51 for acetylation of starch, I, 284, 286 Bourguel s, II, 109, 110, 113 for esterification of cellulose, I, 312 in oxidation of carbohydrates by halogens, III, 177... [Pg.335]

RTILs hold for the preparation of nanomaterials. In some cases, it is known that homogeneous catalysts in RTILS act as nanocluster or nanoparticle catalysts. A recent example is an lr(0) catalyst for acetone hydrogenation. ... [Pg.129]

However, this advance has an important shortcoming the lack of context. More than one idea is expressed in a document a patent on oxidation catalysts, for example, could include examples of the oxidation of methanol to formaldehyde and of 2-propanol to acetone. A simple coordinate search for conversion of methanol to acetone would retrieve such a document from a file that provides no context. [Pg.59]

Dehydrogenation processes for acetone, methyl isobutyl ketone [108-10-1], and higher ketones (qv) utilizing, in one process, a copper-based catalyst have been disclosed (18,19). Dehydrogenation reaction is used to study the acid—base character of catalytic sites on a series of oxides (20,21). [Pg.105]

A direct route for acetone from propylene was developed using a homogeneous catalyst similar to Wacker system (PdCl2/CuCl2). The reaction conditions are similar to those used for ethylene oxidation to acetaldehyde. ... [Pg.230]

Neopentyl alcohol, 40, 76 Nickel catalyst for hydrogenation of resorcinol, 41, 56, 57 Nitramines from amines and acetone cyanohydrin nitrate, 43, 84 Nitration, of amines to nitramines by acetone cyanohydrin nitrate, 43, 83... [Pg.118]

As in the case of homogeneous acids as catalyst, we would also benefit from using solid ba.ses instead of dissolved bases as catalyst. A number of industrially important reactions are carried out with bases as catalyst. A well know example is the aldol condensation of acetone to diacetone alcohol, where dissolved NaOH in ethyl alcohol is u.sed as a catalyst at about 200 to 300 ppm level. However, heterogeneous pelleted sodamide can be used as a catalyst for this reaction and it obviates the problem of alkali removal from the product, which would otherwise lead to reversion of diacetone alcohol to acetone during distillation of the product mixture. [Pg.138]

Aromatic amine-Ketone. The interaction between anihne, the simplest of the aromatic amines with acetone in the presence of various catalysts to yield N-isopropylaniline was examined (Table 17.3). Among the catalysts tested, sulfided platinum catalysts were found to be the most active catalysts for this reaction. [Pg.161]

The activity of both Pd and sulfided Pt catalysts for the synthesis of N-(l,3-dimethylbutyl)-N-phenylamine from aniline and MIBK was lower than that with acetone. This could be attributed to the steric hindrance effect (14). The selectivity over sulfided Pt catalysts was higher compared to unsulfided Pd catalysts due to formation of byproducts as with aniline-acetone reaction. [Pg.163]

Lewis-Acid Catalyzed. Recently, various Lewis acids have been examined as catalyst for the aldol reaction. In the presence of complexes of zinc with aminoesters or aminoalcohols, the dehydration can be avoided and the aldol addition becomes essentially quantitative (Eq. 8.97).245 A microporous coordination polymer obtained by treating anthracene- is (resorcinol) with La(0/Pr)3 possesses catalytic activity for ketone enolization and aldol reactions in pure water at neutral pH.246 The La network is stable against hydrolysis and maintains microporosity and reversible substrate binding that mimicked an enzyme. Zn complexes of proline, lysine, and arginine were found to be efficient catalysts for the aldol addition of p-nitrobenzaldehyde and acetone in an aqueous medium to give quantitative yields and the enantiomeric excesses were up to 56% with 5 mol% of the catalysts at room temperature.247... [Pg.268]

A N -Carbonyldipyrazole reacts with ketones such as acetone, methyl ethyl ketone, and cyclic ketones, as well as such aldehydes as acetaldehyde and benzaldehyde to give dipyrazolylalkanes, also in the presence of catalyst, for example cobalt chloride.[293,[3°3... [Pg.391]

Isopropylidene acetals are convenient protecting groups in carbohydrate chemistry, particularly for the protection of 1,2- and 1,3-diols, and are readily formed by reaction of the diol with acetone or 2,2-dimethoxypropane under acidic conditions. Several protic and Lewis acids have been reported as catalysts for this purpose.98... [Pg.57]

Rh(COD)(PPh3)2]BF4 has been shown to be a good catalyst for reductive ami-nation of acetone with 4-anilino-aniline to give the commercial product 3-IPPD. In laboratory-scale comparative experiments, this catalyst - both in homogeneous phase or immobilized on Montmorillonite K10 clay - was found to be superior to the commercially applied Pt/C catalyst (Scheme 15.11) [80]. [Pg.439]


See other pages where Catalysts, for acetonation is mentioned: [Pg.51]    [Pg.237]    [Pg.292]    [Pg.51]    [Pg.237]    [Pg.292]    [Pg.529]    [Pg.437]    [Pg.487]    [Pg.174]    [Pg.234]    [Pg.558]    [Pg.565]    [Pg.887]    [Pg.192]    [Pg.268]    [Pg.300]    [Pg.150]    [Pg.267]    [Pg.243]    [Pg.201]    [Pg.228]    [Pg.47]    [Pg.159]    [Pg.481]    [Pg.528]    [Pg.151]    [Pg.234]    [Pg.368]    [Pg.369]    [Pg.258]    [Pg.93]    [Pg.57]    [Pg.55]    [Pg.19]    [Pg.69]    [Pg.244]    [Pg.248]    [Pg.384]   
See also in sourсe #XX -- [ Pg.51 ]




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